| WC Qualifiers South America | M. | W | D | L | goals | |||
| at home | 13 | 6 | 6 | 1 | 16 | : | 7 | |
| Away | 12 | 1 | 2 | 9 | 9 | : | 27 | |
| Neutral Place | 1 | 0 | 0 | 1 | 1 | : | 2 | |
| ∑ | 26 | 7 | 8 | 11 | 26 | : | 36 | |
| Friendlies | M. | W | D | L | goals | |||
| at home | 7 | 4 | 2 | 1 | 10 | : | 5 | |
| Away | 5 | 0 | 2 | 3 | 2 | : | 9 | |
| Neutral Place | 1 | 0 | 0 | 1 | 1 | : | 2 | |
| ∑ | 13 | 4 | 4 | 5 | 13 | : | 16 | |
| Copa América | M. | W | D | L | goals | |||
| at home | 1 | 0 | 0 | 1 | 0 | : | 3 | |
| Away | 7 | 0 | 1 | 6 | 4 | : | 24 | |
| Neutral Place | 7 | 1 | 0 | 6 | 11 | : | 20 | |
| ∑ | 15 | 1 | 1 | 13 | 15 | : | 47 | |
| overall | M. | W | D | L | goals | |||
| at home | 21 | 10 | 8 | 3 | 26 | : | 15 | |
| Away | 24 | 1 | 5 | 18 | 15 | : | 60 | |
| Neutral Place | 9 | 1 | 0 | 8 | 13 | : | 24 | |
| ∑ | 54 | 12 | 13 | 29 | 54 | : | 99 | |
| Friendlies | |||||
| 2012 | August | Ecuador | - | Chile | 3:0 (2:0) |
| 2005 | February | Chile | - | Ecuador | 3:0 (2:0) |
| 1999 | June | Chile | - | Ecuador | 0:0 (0:0) |
| 1993 | June | Ecuador | - | Chile | 1:2 (0:2) |
| 1991 | June | Chile | - | Ecuador | 3:1 (3:0) |
| 1991 | June | Ecuador | - | Chile | 2:1 (0:1) |
| 1989 | January | Ecuador | - | Chile | 1:0 (0:0) |
| 1988 | September | Ecuador | - | Chile | 4:3 (0:0, 0:0, 0:0) pso |
| 1988 | September | Chile | - | Ecuador | 3:1 (1:0) |
| 1979 | June | Ecuador | - | Chile | 2:1 (0:1) |
| 1979 | June | Chile | - | Ecuador | 0:0 (0:0) |
| 1973 | April | Ecuador | - | Chile | 1:1 (0:1) |
| 1972 | June | Chile | - | Ecuador | 2:1 (1:0) |
| Copa América | |||||
| 2019 Brazil | Group C | Ecuador | - | Chile | 1:2 (1:1) |
| 2015 Chile | Group A | Chile | - | Ecuador | 2:0 (0:0) |
| 2007 Venezuela | Group B | Ecuador | - | Chile | 2:3 (2:1) |
| 2001 Colombia | Group A | Ecuador | - | Chile | 1:4 (0:1) |
| 1997 Bolivia | Group A | Chile | - | Ecuador | 1:2 (0:1) |
| 1989 Brazil | Group 2 | Chile | - | Ecuador | 2:1 (1:0) |
| 1957 Peru | Final round | Chile | - | Ecuador | 2:2 (2:0) |
| 1955 Chile | Final round | Chile | - | Ecuador | 7:1 (4:0) |
| 1953 Peru | Final round | Chile | - | Ecuador | 3:0 (1:0) |
| 1949 Brazil | Final round | Chile | - | Ecuador | 1:0 (1:0) |
| 1947 Ecuador | Final round | Ecuador | - | Chile | 0:3 (0:0) |
| 1945 Chile | Final round | Chile | - | Ecuador | 6:3 (3:0) |
| 1942 Uruguay | Final round | Chile | - | Ecuador | 2:1 (2:0) |
| 1941 Chile | Final round | Chile | - | Ecuador | 5:0 (4:0) |
| 1939 Peru | Final round | Chile | - | Ecuador | 4:1 (3:0) |
|
For games that were decided on penalties the score after 120 minutes will be included in the ranking |
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