| Squad | Appearances | ||
| sorting |
| Name |  |
 |
 |
 |
 |
 |
 |
 |
 |
| Juan Mata | 884' | 12 | 10 | 2 | 7 | 5 | 3 | - | - |
| Joaquín | 641' | 11 | 7 | 4 | 5 | 3 | 2 | - | - |
| Hedwiges Maduro | 754' | 11 | 7 | 4 | 1 | 1 | 1 | - | - |
| David Villa | 709' | 10 | 7 | 3 | 1 | 6 | 2 | - | 1 |
| Pablo Hernández | 699' | 10 | 7 | 3 | 2 | 2 | 4 | - | - |
| Jordi Alba | 449' | 9 | 4 | 5 | 2 | - | 2 | - | - |
| Miguel | 750' | 8 | 8 | - | - | - | 1 | - | - |
| Navarro | 640' | 8 | 7 | 1 | - | 1 | - | - | - |
| Rubén Baraja | 593' | 8 | 7 | 1 | 1 | - | 2 | 1 | - |
| Éver Banega | 481' | 7 | 5 | 2 | - | - | 3 | - | 1 |
| César Sánchez | 660' | 7 | 7 | - | - | - | 1 | - | - |
| David Silva | 559' | 7 | 7 | - | 1 | 1 | 2 | 1 | - |
| Marchena | 566' | 7 | 7 | - | 3 | - | 1 | - | - |
| Nikola Žigić | 413' | 7 | 5 | 2 | 3 | 1 | - | - | - |
| Alexis | 471' | 6 | 5 | 1 | 2 | - | 1 | - | - |
| Bruno Saltor | 496' | 6 | 6 | - | 1 | 1 | 3 | - | - |
| Dealbert | 570' | 6 | 6 | - | - | - | - | - | - |
| Albelda | 469' | 5 | 5 | - | 1 | - | 2 | - | - |
| Jérémy Mathieu | 365' | 5 | 5 | - | 2 | - | 3 | - | - |
| Moyá | 450' | 5 | 5 | - | - | - | 1 | - | - |
| Manuel Fernandes | 217' | 4 | 2 | 2 | 1 | 1 | - | - | - |
| Míchel | 161' | 3 | 2 | 1 | 1 | - | - | - | - |
| Nicolás Fedor | 84' | 2 | 1 | 1 | 1 | - | 1 | - | - |
| Vicente | 34' | 2 | - | 2 | - | - | - | - | - |
| Del Horno | 20' | 1 | - | 1 | - | - | 1 | - | - |
| Daniel Olcina | - | - | - | - | - | - | - | - | - |
| Alejandro Domínguez | - | - | - | - | - | - | - | - | - |
| Joel Johnson | - | - | - | - | - | - | - | - | - |
| Lillo | - | - | - | - | - | - | - | - | - |
| Víctor Fernández | - | - | - | - | - | - | - | - | - |
Spain