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| 1st(1st leg) | PFC Litex Lovech | - | RC Strasbourg | 0:2 (0:1) | ||
| 2nd (2nd leg) | RC Strasbourg | - | PFC Litex Lovech | 0:0 (0:0) | ||
| 1st(1st leg): 15/02/2006 14:30 | 2nd (2nd leg): 23/02/2006 18:00 | Winner: RC Strasbourg | ||||
| 1st(1st leg) | Lokomotiv Moskva | - | Sevilla FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Lokomotiv Moskva | 2:0 (1:0) | ||
| 1st(1st leg): 15/02/2006 16:30 | 2nd (2nd leg): 23/02/2006 20:30 | Winner: Sevilla FC | ||||
| 1st(1st leg) | FC Artmedia Bratislava | - | Levski Sofia | 0:1 (0:1) | ||
| 2nd (2nd leg) | Levski Sofia | - | FC Artmedia Bratislava | 2:0 (2:0) | ||
| 1st(1st leg): 15/02/2006 16:30 | 2nd (2nd leg): 23/02/2006 16:00 | Winner: Levski Sofia | ||||
| 1st(1st leg) | Hertha BSC | - | Rapid Bucureşti | 0:1 (0:0) | ||
| 2nd (2nd leg) | Rapid Bucureşti | - | Hertha BSC | 2:0 (0:0) | ||
| 1st(1st leg): 15/02/2006 17:00 | 2nd (2nd leg): 23/02/2006 15:15 | Winner: Rapid Bucureşti | ||||
| 1st(1st leg) | FC Basel 1893 | - | AS Monaco | 1:0 (0:0) | ||
| 2nd (2nd leg) | AS Monaco | - | FC Basel 1893 | 1:1 (1:0) | ||
| 1st(1st leg): 15/02/2006 17:00 | 2nd (2nd leg): 23/02/2006 19:45 | Winner: FC Basel 1893 | ||||
| 1st(1st leg) | Lille OSC | - | Shakhtar Donetsk | 3:2 (1:0) | ||
| 2nd (2nd leg) | Shakhtar Donetsk | - | Lille OSC | 0:0 (0:0) | ||
| 1st(1st leg): 15/02/2006 18:00 | 2nd (2nd leg): 23/02/2006 17:00 | Winner: Lille OSC | ||||
| 1st(1st leg) | Rosenborg BK | - | Zenit St. Petersburg | 0:2 (0:2) | ||
| 2nd (2nd leg) | Zenit St. Petersburg | - | Rosenborg BK | 2:1 (0:1) | ||
| 1st(1st leg): 15/02/2006 18:30 | 2nd (2nd leg): 23/02/2006 17:00 | Winner: Zenit St. Petersburg | ||||
| 1st(1st leg) | FC Schalke 04 | - | Espanyol Barcelona | 2:1 (0:1) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | FC Schalke 04 | 0:3 (0:0) | ||
| 1st(1st leg): 15/02/2006 19:00 | 2nd (2nd leg): 23/02/2006 20:45 | Winner: FC Schalke 04 | ||||
| 1st(1st leg) | sc Heerenveen | - | FC Steaua Bucureşti | 1:3 (1:1) | ||
| 2nd (2nd leg) | FC Steaua Bucureşti | - | sc Heerenveen | 0:1 (0:0) | ||
| 1st(1st leg): 15/02/2006 19:30 | 2nd (2nd leg): 23/02/2006 17:00 | Winner: FC Steaua Bucureşti | ||||
| 1st(1st leg) | Bolton Wanderers | - | Olympique Marseille | 0:0 (0:0) | ||
| 2nd (2nd leg) | Olympique Marseille | - | Bolton Wanderers | 2:1 (1:1) | ||
| 1st(1st leg): 15/02/2006 19:45 | 2nd (2nd leg): 23/02/2006 19:45 | Winner: Olympique Marseille | ||||
| 1st(1st leg) | Udinese Calcio | - | RC Lens | 3:0 (1:0) | ||
| 2nd (2nd leg) | RC Lens | - | Udinese Calcio | 1:0 (0:0) | ||
| 1st(1st leg): 15/02/2006 19:45 | 2nd (2nd leg): 23/02/2006 19:45 | Winner: Udinese Calcio | ||||
| 1st(1st leg) | Club Brugge KV | - | AS Roma | 1:2 (0:1) | ||
| 2nd (2nd leg) | AS Roma | - | Club Brugge KV | 2:1 (0:0) | ||
| 1st(1st leg): 15/02/2006 19:45 | 2nd (2nd leg): 23/02/2006 20:00 | Winner: AS Roma | ||||
| 1st(1st leg) | Real Betis | - | AZ Alkmaar | 2:0 (0:0) | ||
| 2nd (2nd leg) | AZ Alkmaar | - | Real Betis | 2:1 (2:0, 2:0) aet | ||
| 1st(1st leg): 15/02/2006 20:30 | 2nd (2nd leg): 23/02/2006 19:45 | Winner: Real Betis | ||||
| 1st(1st leg) | FC Thun | - | Hamburger SV | 1:0 (1:0) | ||
| 2nd (2nd leg) | Hamburger SV | - | FC Thun | 2:0 (2:0) | ||
| 1st(1st leg): 16/02/2006 17:30 | 2nd (2nd leg): 23/02/2006 17:30 | Winner: Hamburger SV | ||||
| 1st(1st leg) | VfB Stuttgart | - | Middlesbrough FC | 1:2 (0:1) | ||
| 2nd (2nd leg) | Middlesbrough FC | - | VfB Stuttgart | 0:1 (0:1) | ||
| 1st(1st leg): 16/02/2006 19:45 | 2nd (2nd leg): 23/02/2006 19:45 | Winner: Middlesbrough FC | ||||
| 1st(1st leg) | Slavia Praha | - | US Palermo | 2:1 (1:1) | ||
| 2nd (2nd leg) | US Palermo | - | Slavia Praha | 1:0 (0:0) | ||
| 1st(1st leg): 16/02/2006 19:45 | 2nd (2nd leg): 23/02/2006 15:00 | Winner: US Palermo | ||||
