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| 11/01/2021 | 21:15 | CS Marítimo | - | Sporting CP | 2:0 (0:0) | |
| 12/01/2021 | 14:00 | Rio Ave FC | - | GD Estoril | 1:2 (0:2) | |
| 17:00 | Moreirense FC | - | CD Santa Clara | 1:2 (0:1) | ||
| 18:00 | CD Nacional | - | FC Porto | 2:4 (1:1, 2:2) aet | ||
| 21:15 | Estrela Amadora | - | SL Benfica | 0:4 (0:1) | ||
| 13/01/2021 | 15:30 | Sporting Braga | - | União Torreense | 5:0 (2:0) | |
| 14/01/2021 | 14:00 | AD Fafe | - | Belenenses SAD | 2:3 (2:0, 2:2) aet | |
| 20:30 | Gil Vicente | - | Académico de Viseu | 3:2 (1:1, 2:2) aet |
