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| 1st(1st leg) | CF América | - | Santos Laguna | 5:3 (1:1) | ||
| 2nd (2nd leg) | Santos Laguna | - | CF América | 3:1 (1:0) | ||
| 1st(1st leg): 01/05/2014 02:00 | 2nd (2nd leg): 04/05/2014 03:00 | Winner: Santos Laguna | ||||
| 1st(1st leg) | Club León | - | Cruz Azul | 1:1 (1:1) | ||
| 2nd (2nd leg) | Cruz Azul | - | Club León | 2:2 (2:1) | ||
| 1st(1st leg): 01/05/2014 04:00 | 2nd (2nd leg): 04/05/2014 01:00 | Winner: Club León | ||||
| 1st(1st leg) | CF Pachuca | - | Pumas UNAM | 1:1 (0:0) | ||
| 2nd (2nd leg) | Pumas UNAM | - | CF Pachuca | 2:4 (2:2) | ||
| 1st(1st leg): 02/05/2014 02:00 | 2nd (2nd leg): 04/05/2014 23:00 | Winner: CF Pachuca | ||||
| 1st(1st leg) | Club Tijuana | - | Deportivo Toluca | 0:0 (0:0) | ||
| 2nd (2nd leg) | Deportivo Toluca | - | Club Tijuana | 3:1 (1:0) | ||
| 1st(1st leg): 02/05/2014 04:00 | 2nd (2nd leg): 04/05/2014 18:00 | Winner: Deportivo Toluca | ||||
