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| 1st(1st leg) | Olympiakos Volou | - | Asteras Tripolis | 1:1 (1:0) | ||
| 2nd (2nd leg) | Asteras Tripolis | - | Olympiakos Volou | 2:0 (0:0) | ||
| 1st(1st leg): 09/01/2013 15:00 | 2nd (2nd leg): 23/01/2013 18:00 | Winner: Asteras Tripolis | ||||
| 1st(1st leg) | Panathinaikos | - | Platanias Chanion | 2:1 (1:0) | ||
| 2nd (2nd leg) | Platanias Chanion | - | Panathinaikos | 1:0 (0:0) | ||
| 1st(1st leg): 09/01/2013 18:00 | 2nd (2nd leg): 23/01/2013 15:00 | Winner: Platanias Chanion | ||||
| 1st(1st leg) | PAS Giannina | - | Fostiras FC | 2:0 (1:0) | ||
| 2nd (2nd leg) | Fostiras FC | - | PAS Giannina | 2:3 (1:2) | ||
| 1st(1st leg): 10/01/2013 15:00 | 2nd (2nd leg): 24/01/2013 15:00 | Winner: PAS Giannina | ||||
| 1st(1st leg) | GS Kallithea | - | PAOK Saloniki | 2:0 (0:0) | ||
| 2nd (2nd leg) | PAOK Saloniki | - | GS Kallithea | 6:0 (5:0) | ||
| 1st(1st leg): 10/01/2013 18:00 | 2nd (2nd leg): 24/01/2013 18:00 | Winner: PAOK Saloniki | ||||
| 1st(1st leg) | Apollon Smyrnis | - | Panthrakikos | 1:1 (0:0) | ||
| 2nd (2nd leg) | Panthrakikos | - | Apollon Smyrnis | 4:1 (2:0) | ||
| 1st(1st leg): 16/01/2013 15:00 | 2nd (2nd leg): 31/01/2013 18:00 | Winner: Panthrakikos | ||||
| 1st(1st leg) | Olympiakos Piraeus | - | AO Kavala | 2:0 (0:0) | ||
| 2nd (2nd leg) | AO Kavala | - | Olympiakos Piraeus | 0:1 (0:1) | ||
| 1st(1st leg): 16/01/2013 18:00 | 2nd (2nd leg): 30/01/2013 18:00 | Winner: Olympiakos Piraeus | ||||
| 1st(1st leg) | Levadiakos | - | AO Kerkyra | 2:1 (1:1) | ||
| 2nd (2nd leg) | AO Kerkyra | - | Levadiakos | 0:1 (0:1) | ||
| 1st(1st leg): 17/01/2013 15:00 | 2nd (2nd leg): 31/01/2013 12:00 | Winner: Levadiakos | ||||
| 1st(1st leg) | Veria FC | - | Skoda Xanthi | 2:1 (1:0) | ||
| 2nd (2nd leg) | Skoda Xanthi | - | Veria FC | 0:2 (0:1) | ||
| 1st(1st leg): 17/01/2013 18:00 | 2nd (2nd leg): 30/01/2013 15:00 | Winner: Veria FC | ||||
