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| 19/09/2006 | 18:30 | FC Istres | - | Lille OSC | 0:1 (0:0) | |
| 19:00 | Dijon FCO | - | Amiens SC | 2:1 (0:0) | ||
| 19:00 | Stade de Reims | - | Clermont Foot Auvergne | 3:1 (1:0) | ||
| 20:00 | FC Nantes | - | Toulouse FC | 0:2 (0:1) | ||
| 20/09/2006 | 15:00 | AS Nancy Lorraine | - | OGC Nice | 1:0 (1:0) | |
| 19:00 | US Créteil-Lusitanos | - | RC Lens | 1:4 (1:0) | ||
| 20:00 | CS Sedan | - | FC Sochaux | 0:1 (0:1) | ||
| 20:00 | ESTAC Troyes | - | Le Mans UC 72 | 1:2 (1:1) | ||
| 20:00 | Paris Saint-Germain | - | FC Lorient | 3:1 (0:1) | ||
| 20:00 | FC Sète | - | AS Saint-Étienne | 1:4 (1:3) | ||
| 20:00 | AJ Auxerre | - | RC Strasbourg | 2:0 (1:0) | ||
| 20:00 | Valenciennes FC | - | AS Monaco | 4:5 (0:0, 0:0, 0:0) pso | ||
| 20:00 | Montpellier HSC | - | Olympique Marseille | 1:2 (0:2) | ||
| 20:00 | Stade Rennais | - | FC Libourne-Saint-Seurin | 2:1 (2:0) |
