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| 1st(1st leg) | Dinamo Kiev | - | Club Brugge KV | 1:1 (0:0) | ||
| 2nd (2nd leg) | Club Brugge KV | - | Dinamo Kiev | 0:1 (0:0) | ||
| 1st(1st leg): 18/02/2021 15:00 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: Dinamo Kiev | ||||
| 1st(1st leg) | Wolfsberger AC | - | Tottenham Hotspur | 1:4 (0:3) | ||
| 2nd (2nd leg) | Tottenham Hotspur | - | Wolfsberger AC | 4:0 (1:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 24/02/2021 17:00 | Winner: Tottenham Hotspur | ||||
| 1st(1st leg) | Real Sociedad | - | Manchester United | 0:4 (0:1) | ||
| 2nd (2nd leg) | Manchester United | - | Real Sociedad | 0:0 (0:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: Manchester United | ||||
| 1st(1st leg) | Crvena Zvezda | - | AC Milan | 2:2 (0:1) | ||
| 2nd (2nd leg) | AC Milan | - | Crvena Zvezda | 1:1 (1:1) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: AC Milan | ||||
| 1st(1st leg) | Slavia Praha | - | Leicester City | 0:0 (0:0) | ||
| 2nd (2nd leg) | Leicester City | - | Slavia Praha | 0:2 (0:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: Slavia Praha | ||||
| 1st(1st leg) | Sporting Braga | - | AS Roma | 0:2 (0:1) | ||
| 2nd (2nd leg) | AS Roma | - | Sporting Braga | 3:1 (1:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: AS Roma | ||||
| 1st(1st leg) | FK Krasnodar | - | Dinamo Zagreb | 2:3 (1:1) | ||
| 2nd (2nd leg) | Dinamo Zagreb | - | FK Krasnodar | 1:0 (1:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: Dinamo Zagreb | ||||
| 1st(1st leg) | BSC Young Boys | - | Bayer Leverkusen | 4:3 (3:0) | ||
| 2nd (2nd leg) | Bayer Leverkusen | - | BSC Young Boys | 0:2 (0:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: BSC Young Boys | ||||
| 1st(1st leg) | Olympiakos Piraeus | - | PSV Eindhoven | 4:2 (3:2) | ||
| 2nd (2nd leg) | PSV Eindhoven | - | Olympiakos Piraeus | 2:1 (2:0) | ||
| 1st(1st leg): 18/02/2021 17:55 | 2nd (2nd leg): 25/02/2021 20:00 | Winner: Olympiakos Piraeus | ||||
| 1st(1st leg) | SL Benfica | - | Arsenal FC | 1:1 (0:0) | ||
| 2nd (2nd leg) | Arsenal FC | - | SL Benfica | 3:2 (1:1) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: Arsenal FC | ||||
| 1st(1st leg) | Royal Antwerp FC | - | Rangers FC | 3:4 (2:1) | ||
| 2nd (2nd leg) | Rangers FC | - | Royal Antwerp FC | 5:2 (1:1) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: Rangers FC | ||||
| 1st(1st leg) | RB Salzburg | - | Villarreal CF | 0:2 (0:1) | ||
| 2nd (2nd leg) | Villarreal CF | - | RB Salzburg | 2:1 (1:1) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Molde FK | - | 1899 Hoffenheim | 3:3 (1:3) | ||
| 2nd (2nd leg) | 1899 Hoffenheim | - | Molde FK | 0:2 (0:1) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: Molde FK | ||||
| 1st(1st leg) | Granada CF | - | SSC Napoli | 2:0 (2:0) | ||
| 2nd (2nd leg) | SSC Napoli | - | Granada CF | 2:1 (1:1) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: Granada CF | ||||
| 1st(1st leg) | Maccabi Tel Aviv | - | Shakhtar Donetsk | 0:2 (0:1) | ||
| 2nd (2nd leg) | Shakhtar Donetsk | - | Maccabi Tel Aviv | 1:0 (0:0) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: Shakhtar Donetsk | ||||
| 1st(1st leg) | Lille OSC | - | AFC Ajax | 1:2 (0:0) | ||
| 2nd (2nd leg) | AFC Ajax | - | Lille OSC | 2:1 (1:0) | ||
| 1st(1st leg): 18/02/2021 20:00 | 2nd (2nd leg): 25/02/2021 17:55 | Winner: AFC Ajax | ||||
