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| 1st(1st leg) | AZ Alkmaar | - | Valencia CF | 2:1 (1:0) | ||
| 2nd (2nd leg) | Valencia CF | - | AZ Alkmaar | 4:0 (2:0) | ||
| 1st(1st leg): 29/03/2012 20:05 | 2nd (2nd leg): 05/04/2012 20:05 | Winner: Valencia CF | ||||
| 1st(1st leg) | FC Schalke 04 | - | Athletic Bilbao | 2:4 (1:1) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | FC Schalke 04 | 2:2 (1:1) | ||
| 1st(1st leg): 29/03/2012 20:05 | 2nd (2nd leg): 05/04/2012 20:05 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Sporting CP | - | Metalist Kharkiv | 2:1 (0:0) | ||
| 2nd (2nd leg) | Metalist Kharkiv | - | Sporting CP | 1:1 (0:1) | ||
| 1st(1st leg): 29/03/2012 20:05 | 2nd (2nd leg): 05/04/2012 20:05 | Winner: Sporting CP | ||||
| 1st(1st leg) | Atlético Madrid | - | Hannover 96 | 2:1 (1:1) | ||
| 2nd (2nd leg) | Hannover 96 | - | Atlético Madrid | 1:2 (0:0) | ||
| 1st(1st leg): 29/03/2012 20:05 | 2nd (2nd leg): 05/04/2012 20:05 | Winner: Atlético Madrid | ||||
