02/01/1966 RCD Mallorca - FC Barcelona 1:2 (0:1)
Atlético Madrid - Real Zaragoza 0:1 (0:0)
Córdoba CF - Elche CF 1:0 (0:0)
Pontevedra CF - CD Málaga 3:0 (2:0)
Real Betis - Athletic Bilbao 2:0 (0:0)
Espanyol Barcelona - UD Las Palmas 1:1 (0:0)
CE Sabadell - Real Madrid 1:1 (0:1)
Valencia CF - Sevilla FC 0:1 (0:0)
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# Team M. W D L goals Dif. Pt.
1 Atlético Madrid, Spain Atlético Madrid 16 9 5 2 28:12 16 23:9
2 Pontevedra CF, Spain Pontevedra CF 16 10 2 4 22:11 11 22:10
3 Real Madrid, Spain Real Madrid 16 9 3 4 24:20 4 21:11
4 Valencia CF, Spain Valencia CF 16 9 2 5 26:17 9 20:12
5 FC Barcelona, Spain FC Barcelona 16 8 2 6 25:19 6 18:14
6 Athletic Bilbao, Spain Athletic Bilbao 16 8 2 6 23:17 6 18:14
7 Real Zaragoza, Spain Real Zaragoza 16 6 5 5 29:20 9 17:15
8 Elche CF, Spain Elche CF 16 6 4 6 18:21 -3 16:16
9 Córdoba CF, Spain Córdoba CF 16 6 3 7 17:14 3 15:17
10 Espanyol Barcelona, Spain Espanyol Barcelona 16 4 7 5 17:23 -6 15:17
11 CD Málaga, Spain CD Málaga 16 5 4 7 11:17 -6 14:18
12 Sevilla FC, Spain Sevilla FC 16 3 7 6 14:18 -4 13:19
13 UD Las Palmas, Spain UD Las Palmas 16 3 6 7 14:22 -8 12:20
14 Real Betis, Spain Real Betis 16 5 2 9 23:38 -15 12:20
15 RCD Mallorca, Spain RCD Mallorca 16 5 1 10 23:37 -14 11:21
16 CE Sabadell, Spain CE Sabadell 16 3 3 10 15:23 -8 9:23
Primera División
Primera División

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