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| 1st(1st leg) | Valencia CF | - | RC Celta | 1:4 (0:3) | ||
| 2nd (2nd leg) | RC Celta | - | Valencia CF | 2:1 (0:0) | ||
| 1st(1st leg): 03/01/2017 18:00 | 2nd (2nd leg): 12/01/2017 18:00 | Winner: RC Celta | ||||
| 1st(1st leg) | CA Osasuna | - | SD Eibar | 0:3 (0:1) | ||
| 2nd (2nd leg) | SD Eibar | - | CA Osasuna | 0:0 (0:0) | ||
| 1st(1st leg): 03/01/2017 18:00 | 2nd (2nd leg): 12/01/2017 18:00 | Winner: SD Eibar | ||||
| 1st(1st leg) | UD Las Palmas | - | Atlético Madrid | 0:2 (0:1) | ||
| 2nd (2nd leg) | Atlético Madrid | - | UD Las Palmas | 2:3 (0:0) | ||
| 1st(1st leg): 03/01/2017 20:15 | 2nd (2nd leg): 10/01/2017 20:15 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Deportivo La Coruña | - | CD Alavés | 2:2 (0:2) | ||
| 2nd (2nd leg) | CD Alavés | - | Deportivo La Coruña | 1:1 (1:0) | ||
| 1st(1st leg): 03/01/2017 20:15 | 2nd (2nd leg): 11/01/2017 18:00 | Winner: CD Alavés | ||||
| 1st(1st leg) | AD Alcorcón | - | Córdoba CF | 0:0 (0:0) | ||
| 2nd (2nd leg) | Córdoba CF | - | AD Alcorcón | 1:2 (1:0) | ||
| 1st(1st leg): 04/01/2017 18:00 | 2nd (2nd leg): 11/01/2017 18:00 | Winner: AD Alcorcón | ||||
| 1st(1st leg) | Real Sociedad | - | Villarreal CF | 3:1 (2:0) | ||
| 2nd (2nd leg) | Villarreal CF | - | Real Sociedad | 1:1 (1:1) | ||
| 1st(1st leg): 04/01/2017 18:00 | 2nd (2nd leg): 11/01/2017 18:00 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Real Madrid | - | Sevilla FC | 3:0 (3:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Real Madrid | 3:3 (1:0) | ||
| 1st(1st leg): 04/01/2017 20:15 | 2nd (2nd leg): 12/01/2017 20:15 | Winner: Real Madrid | ||||
| 1st(1st leg) | Athletic Club | - | FC Barcelona | 2:1 (2:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | Athletic Club | 3:1 (1:0) | ||
| 1st(1st leg): 05/01/2017 20:15 | 2nd (2nd leg): 11/01/2017 20:15 | Winner: FC Barcelona | ||||
