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| 1st(1st leg) | RC Celta | - | Atlético Madrid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Atlético Madrid | - | RC Celta | 2:3 (1:1) | ||
| 1st(1st leg): 20/01/2016 19:30 | 2nd (2nd leg): 27/01/2016 19:30 | Winner: RC Celta | ||||
| 1st(1st leg) | Athletic Bilbao | - | FC Barcelona | 1:2 (0:2) | ||
| 2nd (2nd leg) | FC Barcelona | - | Athletic Bilbao | 3:1 (0:1) | ||
| 1st(1st leg): 20/01/2016 20:00 | 2nd (2nd leg): 27/01/2016 20:30 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Valencia CF | - | UD Las Palmas | 1:1 (0:1) | ||
| 2nd (2nd leg) | UD Las Palmas | - | Valencia CF | 0:1 (0:1) | ||
| 1st(1st leg): 21/01/2016 19:00 | 2nd (2nd leg): 28/01/2016 20:00 | Winner: Valencia CF | ||||
| 1st(1st leg) | Sevilla FC | - | CD Mirandés | 2:0 (1:0) | ||
| 2nd (2nd leg) | CD Mirandés | - | Sevilla FC | 0:3 (0:1) | ||
| 1st(1st leg): 21/01/2016 20:00 | 2nd (2nd leg): 28/01/2016 19:00 | Winner: Sevilla FC | ||||
