1st(1st leg) Valencia CF - Atlético Madrid 1:1 (0:0)
2nd (2nd leg) Atlético Madrid - Valencia CF 2:0 (0:0)
1st(1st leg): 07/01/2014 21:00 2nd (2nd leg): 14/01/2014 20:30 Winner: Atlético Madrid
1st(1st leg) AD Alcorcón - Espanyol Barcelona 1:0 (0:0)
2nd (2nd leg) Espanyol Barcelona - AD Alcorcón 4:2 (2:1)
1st(1st leg): 08/01/2014 19:00 2nd (2nd leg): 15/01/2014 18:30 Winner: Espanyol Barcelona
1st(1st leg) Real Betis - Athletic Club 1:0 (1:0)
2nd (2nd leg) Athletic Club - Real Betis 2:0 (1:0)
1st(1st leg): 08/01/2014 19:00 2nd (2nd leg): 15/01/2014 18:30 Winner: Athletic Club
1st(1st leg) FC Barcelona - Getafe CF 4:0 (1:0)
2nd (2nd leg) Getafe CF - FC Barcelona 0:2 (0:1)
1st(1st leg): 08/01/2014 21:00 2nd (2nd leg): 16/01/2014 21:00 Winner: FC Barcelona
1st(1st leg) Racing Santander - UD Almería 1:1 (0:1)
2nd (2nd leg) UD Almería - Racing Santander 0:2 (0:0)
1st(1st leg): 08/01/2014 21:00 2nd (2nd leg): 14/01/2014 18:30 Winner: Racing Santander
1st(1st leg) Real Sociedad - Villarreal CF 0:0 (0:0)
2nd (2nd leg) Villarreal CF - Real Sociedad 0:1 (0:1)
1st(1st leg): 09/01/2014 18:30 2nd (2nd leg): 16/01/2014 19:00 Winner: Real Sociedad
1st(1st leg) Rayo Vallecano - Levante UD 0:0 (0:0)
2nd (2nd leg) Levante UD - Rayo Vallecano 1:0 (1:0)
1st(1st leg): 09/01/2014 20:30 2nd (2nd leg): 15/01/2014 20:30 Winner: Levante UD
1st(1st leg) Real Madrid - CA Osasuna 2:0 (1:0)
2nd (2nd leg) CA Osasuna - Real Madrid 0:2 (0:1)
1st(1st leg): 09/01/2014 20:30 2nd (2nd leg): 15/01/2014 20:30 Winner: Real Madrid