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| 1st(1st leg) | Valencia CF | - | Atlético Madrid | 1:1 (0:0) | ||
| 2nd (2nd leg) | Atlético Madrid | - | Valencia CF | 2:0 (0:0) | ||
| 1st(1st leg): 07/01/2014 21:00 | 2nd (2nd leg): 14/01/2014 20:30 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | AD Alcorcón | - | Espanyol Barcelona | 1:0 (0:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | AD Alcorcón | 4:2 (2:1) | ||
| 1st(1st leg): 08/01/2014 19:00 | 2nd (2nd leg): 15/01/2014 18:30 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Real Betis | - | Athletic Bilbao | 1:0 (1:0) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Real Betis | 2:0 (1:0) | ||
| 1st(1st leg): 08/01/2014 19:00 | 2nd (2nd leg): 15/01/2014 18:30 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | FC Barcelona | - | Getafe CF | 4:0 (1:0) | ||
| 2nd (2nd leg) | Getafe CF | - | FC Barcelona | 0:2 (0:1) | ||
| 1st(1st leg): 08/01/2014 21:00 | 2nd (2nd leg): 16/01/2014 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Racing Santander | - | UD Almería | 1:1 (0:1) | ||
| 2nd (2nd leg) | UD Almería | - | Racing Santander | 0:2 (0:0) | ||
| 1st(1st leg): 08/01/2014 21:00 | 2nd (2nd leg): 14/01/2014 18:30 | Winner: Racing Santander | ||||
| 1st(1st leg) | Real Sociedad | - | Villarreal CF | 0:0 (0:0) | ||
| 2nd (2nd leg) | Villarreal CF | - | Real Sociedad | 0:1 (0:1) | ||
| 1st(1st leg): 09/01/2014 18:30 | 2nd (2nd leg): 16/01/2014 19:00 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Rayo Vallecano | - | Levante UD | 0:0 (0:0) | ||
| 2nd (2nd leg) | Levante UD | - | Rayo Vallecano | 1:0 (1:0) | ||
| 1st(1st leg): 09/01/2014 20:30 | 2nd (2nd leg): 15/01/2014 20:30 | Winner: Levante UD | ||||
| 1st(1st leg) | Real Madrid | - | CA Osasuna | 2:0 (1:0) | ||
| 2nd (2nd leg) | CA Osasuna | - | Real Madrid | 0:2 (0:1) | ||
| 1st(1st leg): 09/01/2014 20:30 | 2nd (2nd leg): 15/01/2014 20:30 | Winner: Real Madrid | ||||
