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| 1st(1st leg) | CA Osasuna | - | Valencia CF | 0:2 (0:0) | ||
| 2nd (2nd leg) | Valencia CF | - | CA Osasuna | 2:1 (1:1) | ||
| 1st(1st leg): 11/12/2012 19:00 | 2nd (2nd leg): 08/01/2013 20:30 | Winner: Valencia CF | ||||
| 1st(1st leg) | Córdoba CF | - | FC Barcelona | 0:2 (0:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Córdoba CF | 5:0 (3:0) | ||
| 1st(1st leg): 12/12/2012 19:00 | 2nd (2nd leg): 10/01/2013 20:30 | Winner: FC Barcelona | ||||
| 1st(1st leg) | RCD Mallorca | - | Sevilla FC | 0:5 (0:3) | ||
| 2nd (2nd leg) | Sevilla FC | - | RCD Mallorca | 1:2 (1:0) | ||
| 1st(1st leg): 12/12/2012 19:00 | 2nd (2nd leg): 09/01/2013 18:30 | Winner: Sevilla FC | ||||
| 1st(1st leg) | Atlético Madrid | - | Getafe CF | 3:0 (1:0) | ||
| 2nd (2nd leg) | Getafe CF | - | Atlético Madrid | 0:0 (0:0) | ||
| 1st(1st leg): 12/12/2012 21:00 | 2nd (2nd leg): 10/01/2013 18:30 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | RC Celta | - | Real Madrid | 2:1 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | RC Celta | 4:0 (2:0) | ||
| 1st(1st leg): 12/12/2012 21:00 | 2nd (2nd leg): 09/01/2013 20:30 | Winner: Real Madrid | ||||
| 1st(1st leg) | Levante UD | - | Real Zaragoza | 0:1 (0:0) | ||
| 2nd (2nd leg) | Real Zaragoza | - | Levante UD | 2:0 (1:0) | ||
| 1st(1st leg): 13/12/2012 19:00 | 2nd (2nd leg): 09/01/2013 20:30 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | UD Las Palmas | - | Real Betis | 1:1 (0:0) | ||
| 2nd (2nd leg) | Real Betis | - | UD Las Palmas | 1:0 (0:0) | ||
| 1st(1st leg): 13/12/2012 21:00 | 2nd (2nd leg): 10/01/2013 20:30 | Winner: Real Betis | ||||
| 1st(1st leg) | SD Eibar | - | Málaga CF | 1:1 (0:0) | ||
| 2nd (2nd leg) | Málaga CF | - | SD Eibar | 4:1 (0:1) | ||
| 1st(1st leg): 18/12/2012 19:00 | 2nd (2nd leg): 08/01/2013 18:30 | Winner: Málaga CF | ||||
