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| 1st(1st leg) | Espanyol Barcelona | - | CD Mirandés | 3:2 (0:1) | ||
| 2nd (2nd leg) | CD Mirandés | - | Espanyol Barcelona | 2:1 (0:0) | ||
| 1st(1st leg): 17/01/2012 20:00 | 2nd (2nd leg): 24/01/2012 20:30 | Winner: CD Mirandés | ||||
| 1st(1st leg) | Athletic Bilbao | - | RCD Mallorca | 2:0 (1:0) | ||
| 2nd (2nd leg) | RCD Mallorca | - | Athletic Bilbao | 0:1 (0:0) | ||
| 1st(1st leg): 18/01/2012 19:00 | 2nd (2nd leg): 25/01/2012 19:00 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Real Madrid | - | FC Barcelona | 1:2 (1:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | Real Madrid | 2:2 (2:0) | ||
| 1st(1st leg): 18/01/2012 21:00 | 2nd (2nd leg): 25/01/2012 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Valencia CF | - | Levante UD | 4:1 (3:1) | ||
| 2nd (2nd leg) | Levante UD | - | Valencia CF | 0:3 (0:2) | ||
| 1st(1st leg): 19/01/2012 20:30 | 2nd (2nd leg): 26/01/2012 20:30 | Winner: Valencia CF | ||||
