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| 1st(1st leg) | CE L'Hospitalet | - | FC Barcelona | 0:1 (0:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | CE L'Hospitalet | 9:0 (5:0) | ||
| 1st(1st leg): 09/11/2011 21:00 | 2nd (2nd leg): 22/12/2011 21:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Albacete | - | Atlético Madrid | 2:1 (1:0) | ||
| 2nd (2nd leg) | Atlético Madrid | - | Albacete | 0:1 (0:1) | ||
| 1st(1st leg): 08/12/2011 19:00 | 2nd (2nd leg): 21/12/2011 19:00 | Winner: Albacete | ||||
| 1st(1st leg) | Real Oviedo | - | Athletic Bilbao | 0:1 (0:1) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Real Oviedo | 1:0 (0:0) | ||
| 1st(1st leg): 08/12/2011 21:00 | 2nd (2nd leg): 21/12/2011 21:00 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Cádiz CF | - | Valencia CF | 0:0 (0:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Cádiz CF | 4:0 (3:0) | ||
| 1st(1st leg): 13/12/2011 19:00 | 2nd (2nd leg): 22/12/2011 19:00 | Winner: Valencia CF | ||||
| 1st(1st leg) | SD Ponferradina | - | Real Madrid | 0:2 (0:1) | ||
| 2nd (2nd leg) | Real Madrid | - | SD Ponferradina | 5:1 (2:0) | ||
| 1st(1st leg): 13/12/2011 19:00 | 2nd (2nd leg): 20/12/2011 19:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | CD Mirandés | - | Villarreal CF | 1:1 (1:0) | ||
| 2nd (2nd leg) | Villarreal CF | - | CD Mirandés | 0:2 (0:0) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: CD Mirandés | ||||
| 1st(1st leg) | Real Sociedad | - | Granada CF | 4:1 (2:0) | ||
| 2nd (2nd leg) | Granada CF | - | Real Sociedad | 2:1 (1:0) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Getafe CF | - | Málaga CF | 0:1 (0:0) | ||
| 2nd (2nd leg) | Málaga CF | - | Getafe CF | 2:2 (1:0) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: Málaga CF | ||||
| 1st(1st leg) | RCD Mallorca | - | Sporting Gijón | 0:1 (0:0) | ||
| 2nd (2nd leg) | Sporting Gijón | - | RCD Mallorca | 0:2 (0:1) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 20/12/2011 19:00 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | Deportivo La Coruña | - | Levante UD | 3:1 (2:0) | ||
| 2nd (2nd leg) | Levante UD | - | Deportivo La Coruña | 4:1 (2:1, 3:1) aet | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: Levante UD | ||||
| 1st(1st leg) | Córdoba CF | - | Real Betis | 1:0 (0:0) | ||
| 2nd (2nd leg) | Real Betis | - | Córdoba CF | 2:1 (1:1) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: Córdoba CF | ||||
| 1st(1st leg) | AD Alcorcón | - | Real Zaragoza | 1:1 (1:1) | ||
| 2nd (2nd leg) | Real Zaragoza | - | AD Alcorcón | 0:2 (0:0) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: AD Alcorcón | ||||
| 1st(1st leg) | UD Almería | - | CA Osasuna | 1:3 (0:3) | ||
| 2nd (2nd leg) | CA Osasuna | - | UD Almería | 1:1 (0:0) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: CA Osasuna | ||||
| 1st(1st leg) | RC Celta | - | Espanyol Barcelona | 0:0 (0:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | RC Celta | 4:2 (1:0) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 20/12/2011 19:00 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Racing Santander | - | Rayo Vallecano | 3:2 (1:1) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Racing Santander | 4:3 (3:1) | ||
| 1st(1st leg): 13/12/2011 20:00 | 2nd (2nd leg): 21/12/2011 20:00 | Winner: Racing Santander | ||||
| 1st(1st leg) | CD San Roque | - | Sevilla FC | 0:1 (0:1) | ||
| 2nd (2nd leg) | Sevilla FC | - | CD San Roque | 2:1 (0:0) | ||
| 1st(1st leg): 13/12/2011 21:00 | 2nd (2nd leg): 20/12/2011 21:00 | Winner: Sevilla FC | ||||
