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| 1st(1st leg) | Deportivo La Coruña | - | Real Valladolid | 4:1 (0:1) | ||
| 2nd (2nd leg) | Real Valladolid | - | Deportivo La Coruña | 1:1 (0:1) | ||
| 1st(1st leg): 31/01/2007 19:00 | 2nd (2nd leg): 28/02/2007 19:00 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | Getafe CF | - | CA Osasuna | 3:0 (2:0) | ||
| 2nd (2nd leg) | CA Osasuna | - | Getafe CF | 1:0 (1:0) | ||
| 1st(1st leg): 31/01/2007 19:00 | 2nd (2nd leg): 28/02/2007 19:00 | Winner: Getafe CF | ||||
| 1st(1st leg) | FC Barcelona | - | Real Zaragoza | 0:1 (0:0) | ||
| 2nd (2nd leg) | Real Zaragoza | - | FC Barcelona | 1:2 (0:2) | ||
| 1st(1st leg): 31/01/2007 21:00 | 2nd (2nd leg): 28/02/2007 20:30 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Sevilla FC | - | Real Betis | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Betis | - | Sevilla FC | 0:1 (0:0) | ||
| 1st(1st leg): 01/02/2007 20:00 | 2nd (2nd leg): 20/03/2007 19:00 | Winner: Sevilla FC | ||||
