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| 1st(1st leg) | Atlético Madrid | - | CA Osasuna | 1:1 (0:1) | ||
| 2nd (2nd leg) | CA Osasuna | - | Atlético Madrid | 2:0 (2:0) | ||
| 1st(1st leg): 09/01/2007 20:00 | 2nd (2nd leg): 17/01/2007 20:00 | Winner: CA Osasuna | ||||
| 1st(1st leg) | Málaga CF | - | Real Zaragoza | 0:3 (0:1) | ||
| 2nd (2nd leg) | Real Zaragoza | - | Málaga CF | 0:1 (0:1) | ||
| 1st(1st leg): 10/01/2007 19:00 | 2nd (2nd leg): 17/01/2007 20:00 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | Real Valladolid | - | Villarreal CF | 2:1 (1:1) | ||
| 2nd (2nd leg) | Villarreal CF | - | Real Valladolid | 0:1 (0:1) | ||
| 1st(1st leg): 10/01/2007 19:00 | 2nd (2nd leg): 17/01/2007 20:00 | Winner: Real Valladolid | ||||
| 1st(1st leg) | Rayo Vallecano | - | Sevilla FC | 0:0 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Rayo Vallecano | 3:1 (1:1) | ||
| 1st(1st leg): 10/01/2007 19:00 | 2nd (2nd leg): 17/01/2007 20:00 | Winner: Sevilla FC | ||||
| 1st(1st leg) | RCD Mallorca | - | Deportivo La Coruña | 1:2 (0:0) | ||
| 2nd (2nd leg) | Deportivo La Coruña | - | RCD Mallorca | 1:1 (0:1) | ||
| 1st(1st leg): 10/01/2007 19:00 | 2nd (2nd leg): 17/01/2007 20:00 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | Getafe CF | - | Valencia CF | 1:1 (1:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Getafe CF | 2:4 (1:1) | ||
| 1st(1st leg): 10/01/2007 20:30 | 2nd (2nd leg): 17/01/2007 20:30 | Winner: Getafe CF | ||||
| 1st(1st leg) | CD Alavés | - | FC Barcelona | 0:2 (0:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | CD Alavés | 3:2 (2:2) | ||
| 1st(1st leg): 10/01/2007 20:30 | 2nd (2nd leg): 16/01/2007 20:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Real Betis | - | Real Madrid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | Real Betis | 1:1 (1:1) | ||
| 1st(1st leg): 11/01/2007 20:00 | 2nd (2nd leg): 18/01/2007 20:00 | Winner: Real Betis | ||||
