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| 1st(1st leg) | Zamora CF | - | FC Barcelona | 1:3 (1:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | Zamora CF | 6:0 (4:0) | ||
| 1st(1st leg): 03/01/2006 19:30 | 2nd (2nd leg): 11/01/2006 20:30 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Athletic Club | - | Real Madrid | 0:1 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | Athletic Club | 4:0 (1:0) | ||
| 1st(1st leg): 03/01/2006 21:00 | 2nd (2nd leg): 12/01/2006 20:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | RC Celta | - | Real Betis | 1:1 (1:0) | ||
| 2nd (2nd leg) | Real Betis | - | RC Celta | 0:0 (0:0) | ||
| 1st(1st leg): 04/01/2006 19:00 | 2nd (2nd leg): 11/01/2006 19:00 | Winner: Real Betis | ||||
| 1st(1st leg) | Deportivo La Coruña | - | CA Osasuna | 3:0 (2:0) | ||
| 2nd (2nd leg) | CA Osasuna | - | Deportivo La Coruña | 2:1 (0:0) | ||
| 1st(1st leg): 04/01/2006 19:00 | 2nd (2nd leg): 11/01/2006 19:00 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | Cádiz CF | - | Sevilla FC | 3:2 (2:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Cádiz CF | 0:0 (0:0) | ||
| 1st(1st leg): 04/01/2006 19:00 | 2nd (2nd leg): 11/01/2006 19:00 | Winner: Cádiz CF | ||||
| 1st(1st leg) | Villarreal CF | - | Valencia CF | 0:2 (0:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Villarreal CF | 1:0 (0:0) | ||
| 1st(1st leg): 04/01/2006 20:45 | 2nd (2nd leg): 11/01/2006 20:45 | Winner: Valencia CF | ||||
| 1st(1st leg) | Getafe CF | - | Espanyol Barcelona | 0:1 (0:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Getafe CF | 3:3 (1:2) | ||
| 1st(1st leg): 04/01/2006 20:45 | 2nd (2nd leg): 11/01/2006 21:00 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Real Zaragoza | 0:1 (0:0) | ||
| 2nd (2nd leg) | Real Zaragoza | - | Atlético Madrid | 2:2 (2:1) | ||
| 1st(1st leg): 11/01/2006 20:00 | 2nd (2nd leg): 18/01/2006 19:00 | Winner: Real Zaragoza | ||||
