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| 1st(1st leg) | UDA Gramenet | - | UE Lleida | 2:0 (0:0) | ||
| 2nd (2nd leg) | UE Lleida | - | UDA Gramenet | 1:0 (1:0) | ||
| 1st(1st leg): 11/01/2005 19:30 | 2nd (2nd leg): 18/01/2005 19:30 | Winner: UDA Gramenet | ||||
| 1st(1st leg) | Recreativo Huelva | - | Sevilla FC | 0:2 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | Recreativo Huelva | 2:1 (0:1) | ||
| 1st(1st leg): 11/01/2005 20:00 | 2nd (2nd leg): 18/01/2005 20:00 | Winner: Sevilla FC | ||||
| 1st(1st leg) | CD Mirandés | - | Real Betis | 1:3 (0:0) | ||
| 2nd (2nd leg) | Real Betis | - | CD Mirandés | 0:0 (0:0) | ||
| 1st(1st leg): 12/01/2005 19:00 | 2nd (2nd leg): 19/01/2005 19:00 | Winner: Real Betis | ||||
| 1st(1st leg) | CA Osasuna | - | Getafe CF | 2:0 (0:0) | ||
| 2nd (2nd leg) | Getafe CF | - | CA Osasuna | 3:2 (2:1) | ||
| 1st(1st leg): 12/01/2005 19:00 | 2nd (2nd leg): 19/01/2005 19:00 | Winner: CA Osasuna | ||||
| 1st(1st leg) | Elche CF | - | CD Numancia | 1:0 (1:0) | ||
| 2nd (2nd leg) | CD Numancia | - | Elche CF | 5:3 (0:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 12/01/2005 19:30 | 2nd (2nd leg): 19/01/2005 19:00 | Winner: CD Numancia | ||||
| 1st(1st leg) | Lorca Deportiva | - | Atlético Madrid | 1:3 (0:1) | ||
| 2nd (2nd leg) | Atlético Madrid | - | Lorca Deportiva | 2:0 (0:0) | ||
| 1st(1st leg): 12/01/2005 20:30 | 2nd (2nd leg): 20/01/2005 20:00 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | UD Lanzarote | - | Athletic Bilbao | 2:1 (2:1) | ||
| 2nd (2nd leg) | Athletic Bilbao | - | UD Lanzarote | 6:0 (2:0) | ||
| 1st(1st leg): 12/01/2005 21:00 | 2nd (2nd leg): 19/01/2005 20:30 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Real Valladolid | - | Real Madrid | 0:0 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | Real Valladolid | 1:1 (0:0) | ||
| 1st(1st leg): 13/01/2005 20:00 | 2nd (2nd leg): 19/01/2005 20:30 | Winner: Real Valladolid | ||||
