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| 1st(1st leg) | Espanyol Barcelona | - | SD Compostela | 5:1 (3:0) | ||
| 2nd (2nd leg) | SD Compostela | - | Espanyol Barcelona | 1:0 (0:0) | ||
| 1st(1st leg): 09/02/2000 19:45 | 2nd (2nd leg): 16/02/2000 19:45 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Atlético Madrid | - | Rayo Vallecano | 0:0 (0:0) | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Atlético Madrid | 2:2 (1:1) | ||
| 1st(1st leg): 09/02/2000 20:00 | 2nd (2nd leg): 16/02/2000 20:00 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Real Madrid | - | CP Mérida | 1:0 (0:0) | ||
| 2nd (2nd leg) | CP Mérida | - | Real Madrid | 2:1 (1:0, 1:0) aet | ||
| 1st(1st leg): 09/02/2000 20:00 | 2nd (2nd leg): 17/02/2000 20:30 | Winner: Real Madrid | ||||
| 1st(1st leg) | CA Osasuna | - | FC Barcelona | 0:4 (0:1) | ||
| 2nd (2nd leg) | FC Barcelona | - | CA Osasuna | 2:0 (1:0) | ||
| 1st(1st leg): 10/02/2000 20:30 | 2nd (2nd leg): 16/02/2000 20:00 | Winner: FC Barcelona | ||||
