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| 1st(1st leg) | AD Alcorcón | - | CA Osasuna | 0:1 | ||
| 2nd (2nd leg) | CA Osasuna | - | AD Alcorcón | 5:0 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: CA Osasuna | ||||
| 1st(1st leg) | CP Almería | - | Recreativo Huelva | 1:4 | ||
| 2nd (2nd leg) | Recreativo Huelva | - | CP Almería | 1:0 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Recreativo Huelva | ||||
| 1st(1st leg) | Deportivo Aragón | - | Valencia CF | 1:2 | ||
| 2nd (2nd leg) | Valencia CF | - | Deportivo Aragón | 6:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Valencia CF | ||||
| 1st(1st leg) | Real Betis | - | RCD Mallorca | 1:1 | ||
| 2nd (2nd leg) | RCD Mallorca | - | Real Betis | 3:1 aet | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | Castilla CF | - | Orihuela Deportiva CF | 1:0 | ||
| 2nd (2nd leg) | Orihuela Deportiva CF | - | Castilla CF | 0:0 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Castilla CF | ||||
| 1st(1st leg) | Deportivo La Coruña | - | UE Lleida | 0:1 | ||
| 2nd (2nd leg) | UE Lleida | - | Deportivo La Coruña | 4:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: UE Lleida | ||||
| 1st(1st leg) | SD Eibar | - | Real Zaragoza | 1:2 | ||
| 2nd (2nd leg) | Real Zaragoza | - | SD Eibar | 3:0 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | Xerez CD | - | RC Celta | 0:1 | ||
| 2nd (2nd leg) | RC Celta | - | Xerez CD | 2:0 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: RC Celta | ||||
| 1st(1st leg) | CD Lalín | - | UD Las Palmas | 0:3 | ||
| 2nd (2nd leg) | UD Las Palmas | - | CD Lalín | 11:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 21/11/1985 | Winner: UD Las Palmas | ||||
| 1st(1st leg) | CD Málaga | - | Lorca Deportiva | 1:0 | ||
| 2nd (2nd leg) | Lorca Deportiva | - | CD Málaga | 4:5 pso | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: CD Málaga | ||||
| 1st(1st leg) | RCD Mallorca B | - | Hércules CF | 1:1 | ||
| 2nd (2nd leg) | Hércules CF | - | RCD Mallorca B | 2:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Hércules CF | ||||
| 1st(1st leg) | CD Mensajero | - | CD Logroñés | 0:1 | ||
| 2nd (2nd leg) | CD Logroñés | - | CD Mensajero | 2:0 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 19/11/1985 | Winner: CD Logroñés | ||||
| 1st(1st leg) | CP Mérida | - | Sevilla FC | 0:2 | ||
| 2nd (2nd leg) | Sevilla FC | - | CP Mérida | 4:2 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Sevilla FC | ||||
| 1st(1st leg) | CD Mestalla | - | Racing Santander | 0:3 | ||
| 2nd (2nd leg) | Racing Santander | - | CD Mestalla | 0:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Racing Santander | ||||
| 1st(1st leg) | Real Murcia | - | Real Burgos | 0:0 | ||
| 2nd (2nd leg) | Real Burgos | - | Real Murcia | 2:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Real Burgos | ||||
| 1st(1st leg) | Real Oviedo | - | Real Sociedad | 2:1 | ||
| 2nd (2nd leg) | Real Sociedad | - | Real Oviedo | 2:2 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Real Oviedo | ||||
| 1st(1st leg) | UP Plasencia | - | Espanyol Barcelona | 1:5 | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | UP Plasencia | 3:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | CE Sabadell | - | Granada CF | 4:0 | ||
| 2nd (2nd leg) | Granada CF | - | CE Sabadell | 0:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: CE Sabadell | ||||
| 1st(1st leg) | Real Valladolid | - | Rayo Vallecano | 0:0 | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Real Valladolid | 1:0 aet | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | CD Tenerife | - | Sporting Gijón | 2:0 | ||
| 2nd (2nd leg) | Sporting Gijón | - | CD Tenerife | 2:1 | ||
| 1st(1st leg): 13/11/1985 | 2nd (2nd leg): 27/11/1985 | Winner: CD Tenerife | ||||
