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| 1st(1st leg) | CD Teruel | - | Real Zaragoza | 1:5 | ||
| 2nd (2nd leg) | Real Zaragoza | - | CD Teruel | 3:0 | ||
| 1st(1st leg): 16/10/1985 | 2nd (2nd leg): 23/10/1985 | Winner: Real Zaragoza | ||||
| 1st(1st leg) | Atlético Baleares | - | RCD Mallorca B | 1:2 | ||
| 2nd (2nd leg) | RCD Mallorca B | - | Atlético Baleares | 0:0 | ||
| 1st(1st leg): 16/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: RCD Mallorca B | ||||
| 1st(1st leg) | CD Lugo | - | Deportivo La Coruña | 1:0 | ||
| 2nd (2nd leg) | Deportivo La Coruña | - | CD Lugo | 4:1 | ||
| 1st(1st leg): 22/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Deportivo La Coruña | ||||
| 1st(1st leg) | UE Figueres | - | Espanyol Barcelona | 2:2 | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | UE Figueres | 2:0 | ||
| 1st(1st leg): 22/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Espanyol Barcelona | ||||
| 1st(1st leg) | Club Siero | - | Sporting Gijón | 0:1 | ||
| 2nd (2nd leg) | Sporting Gijón | - | Club Siero | 3:1 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Sporting Gijón | ||||
| 1st(1st leg) | SD Ponferradina | - | Real Valladolid | 1:2 | ||
| 2nd (2nd leg) | Real Valladolid | - | SD Ponferradina | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Real Valladolid | ||||
| 1st(1st leg) | CD Ourense | - | RC Celta | 0:0 | ||
| 2nd (2nd leg) | RC Celta | - | CD Ourense | 1:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: RC Celta | ||||
| 1st(1st leg) | Xerez CD | - | Cádiz CF | 1:1 | ||
| 2nd (2nd leg) | Cádiz CF | - | Xerez CD | 1:3 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Xerez CD | ||||
| 1st(1st leg) | CD Alcoyano | - | Valencia CF | 1:1 | ||
| 2nd (2nd leg) | Valencia CF | - | CD Alcoyano | 2:1 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 30/10/1985 | Winner: Valencia CF | ||||
| 1st(1st leg) | Racing Santander | - | CD Alavés | 1:0 | ||
| 2nd (2nd leg) | CD Alavés | - | Racing Santander | 2:2 aet | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Racing Santander | ||||
| 1st(1st leg) | CD Maspalomas | - | UD Las Palmas | 1:4 | ||
| 2nd (2nd leg) | UD Las Palmas | - | CD Maspalomas | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: UD Las Palmas | ||||
| 1st(1st leg) | Atlético Madrileño | - | Rayo Vallecano | 0:2 | ||
| 2nd (2nd leg) | Rayo Vallecano | - | Atlético Madrileño | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 05/11/1985 | Winner: Rayo Vallecano | ||||
| 1st(1st leg) | RB Linense | - | Sevilla FC | 2:0 | ||
| 2nd (2nd leg) | Sevilla FC | - | RB Linense | 4:1 aet | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Sevilla FC | ||||
| 1st(1st leg) | CF Calvo Sotelo | - | Castilla CF | 0:2 | ||
| 2nd (2nd leg) | Castilla CF | - | CF Calvo Sotelo | 4:1 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Castilla CF | ||||
| 1st(1st leg) | Cartagena FC | - | Orihuela Deportiva CF | 1:2 | ||
| 2nd (2nd leg) | Orihuela Deportiva CF | - | Cartagena FC | 2:2 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Orihuela Deportiva CF | ||||
| 1st(1st leg) | Recreativo Huelva | - | AD Ceuta | 3:0 | ||
| 2nd (2nd leg) | AD Ceuta | - | Recreativo Huelva | 1:2 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Recreativo Huelva | ||||
| 1st(1st leg) | Elche CF | - | Lorca Deportiva | 3:1 | ||
| 2nd (2nd leg) | Lorca Deportiva | - | Elche CF | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Lorca Deportiva | ||||
| 1st(1st leg) | Granada CF | - | Real Jaén | 3:1 | ||
| 2nd (2nd leg) | Real Jaén | - | Granada CF | 1:2 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Granada CF | ||||
| 1st(1st leg) | UD Güímar | - | CD Tenerife | 0:1 | ||
| 2nd (2nd leg) | CD Tenerife | - | UD Güímar | 2:2 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: CD Tenerife | ||||
| 1st(1st leg) | CD Binéfar | - | Deportivo Aragón | 2:3 | ||
| 2nd (2nd leg) | Deportivo Aragón | - | CD Binéfar | 2:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Deportivo Aragón | ||||
| 1st(1st leg) | UE Sant Andreu | - | UE Lleida | 1:5 | ||
| 2nd (2nd leg) | UE Lleida | - | UE Sant Andreu | 7:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: UE Lleida | ||||
| 1st(1st leg) | Albacete | - | Real Murcia | 1:2 | ||
| 2nd (2nd leg) | Real Murcia | - | Albacete | 5:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Real Murcia | ||||
| 1st(1st leg) | UP Langreo | - | Real Oviedo | 1:2 | ||
| 2nd (2nd leg) | Real Oviedo | - | UP Langreo | 4:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Real Oviedo | ||||
| 1st(1st leg) | UD Alzira | - | CD Castellón | 2:1 | ||
| 2nd (2nd leg) | CD Castellón | - | UD Alzira | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: CD Castellón | ||||
| 1st(1st leg) | Real Burgos | - | UD Salamanca | 3:1 | ||
| 2nd (2nd leg) | UD Salamanca | - | Real Burgos | 1:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Real Burgos | ||||
| 1st(1st leg) | CD Ronda | - | CD Málaga | 1:0 | ||
| 2nd (2nd leg) | CD Málaga | - | CD Ronda | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: CD Málaga | ||||
| 1st(1st leg) | AD Sabiñanigo | - | CD Logroñés | 1:0 | ||
| 2nd (2nd leg) | CD Logroñés | - | AD Sabiñanigo | 3:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: CD Logroñés | ||||
| 1st(1st leg) | RCD Mallorca | - | CF Sporting Mahonés | 4:0 | ||
| 2nd (2nd leg) | CF Sporting Mahonés | - | RCD Mallorca | 1:1 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: RCD Mallorca | ||||
| 1st(1st leg) | CP Cacereño | - | UP Plasencia | 1:2 | ||
| 2nd (2nd leg) | UP Plasencia | - | CP Cacereño | 0:0 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: UP Plasencia | ||||
| 1st(1st leg) | Barakaldo CF | - | Rayo Cantabria | 2:0 | ||
| 2nd (2nd leg) | Rayo Cantabria | - | Barakaldo CF | 0:1 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: Barakaldo CF | ||||
| 1st(1st leg) | SD Eibar | - | CD Basconia | 0:0 | ||
| 2nd (2nd leg) | CD Basconia | - | SD Eibar | 1:4 | ||
| 1st(1st leg): 23/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: SD Eibar | ||||
| 1st(1st leg) | CD Banyoles | - | CE Sabadell | 1:4 | ||
| 2nd (2nd leg) | CE Sabadell | - | CD Banyoles | 4:0 | ||
| 1st(1st leg): 31/10/1985 | 2nd (2nd leg): 06/11/1985 | Winner: CE Sabadell | ||||
