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| 1st(1st leg) | Real Madrid | - | Athletic Bilbao | 1:0 | ||
| 2nd (2nd leg) | Athletic Bilbao | - | Real Madrid | 2:0 aet | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: Athletic Bilbao | ||||
| 1st(1st leg) | Real Sociedad | - | CE Sabadell | 1:0 | ||
| 2nd (2nd leg) | CE Sabadell | - | Real Sociedad | 0:0 | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: Real Sociedad | ||||
| 1st(1st leg) | Real Betis | - | RCD Mallorca | 4:0 | ||
| 2nd (2nd leg) | RCD Mallorca | - | Real Betis | 2:1 | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: Real Betis | ||||
| 1st(1st leg) | FC Barcelona | - | Hércules CF | 5:0 | ||
| 2nd (2nd leg) | Hércules CF | - | FC Barcelona | 1:0 | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Sporting Gijón | - | Valencia CF | 0:0 | ||
| 2nd (2nd leg) | Valencia CF | - | Sporting Gijón | 1:4 pso | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: Sporting Gijón | ||||
| 1st(1st leg) | Deportivo La Coruña | - | Atlético Madrid | 1:1 | ||
| 2nd (2nd leg) | Atlético Madrid | - | Deportivo La Coruña | 5:2 | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | CD Castellón | - | CD Tenerife | 2:0 | ||
| 2nd (2nd leg) | CD Tenerife | - | CD Castellón | 2:2 | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: CD Castellón | ||||
| 1st(1st leg) | Real Zaragoza | - | Cádiz CF | 1:2 | ||
| 2nd (2nd leg) | Cádiz CF | - | Real Zaragoza | 3:5 pso | ||
| 1st(1st leg): 13/03/1985 | 2nd (2nd leg): 03/04/1985 | Winner: Real Zaragoza | ||||
