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| 1st(1st leg) | Corinthians SP | - | Estudiantes | 1:0 (1:0) | ||
| 2nd (2nd leg) | Estudiantes | - | Corinthians SP | 2:3 (1:0, 1:0) pso | ||
| 1st(1st leg): 23/08/2023 01:30 | 2nd (2nd leg): 30/08/2023 01:30 | Winner: Corinthians SP | ||||
| 1st(1st leg) | Botafogo - RJ | - | Defensa y Justicia | 1:1 (0:0) | ||
| 2nd (2nd leg) | Defensa y Justicia | - | Botafogo - RJ | 2:1 (1:1) | ||
| 1st(1st leg): 23/08/2023 23:00 | 2nd (2nd leg): 30/08/2023 23:00 | Winner: Defensa y Justicia | ||||
| 1st(1st leg) | América - MG | - | Fortaleza - CE | 1:3 (0:3) | ||
| 2nd (2nd leg) | Fortaleza - CE | - | América - MG | 2:1 (1:0) | ||
| 1st(1st leg): 24/08/2023 23:00 | 2nd (2nd leg): 31/08/2023 23:00 | Winner: Fortaleza - CE | ||||
| 1st(1st leg) | LDU Quito | - | São Paulo FC | 2:1 (2:0) | ||
| 2nd (2nd leg) | São Paulo FC | - | LDU Quito | 4:5 (0:0, 1:0) pso | ||
| 1st(1st leg): 24/08/2023 23:00 | 2nd (2nd leg): 31/08/2023 23:00 | Winner: LDU Quito | ||||
