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| 1st(1st leg) | Bahia - BA | - | Unión de Santa Fe | 1:0 (0:0) | ||
| 2nd (2nd leg) | Unión de Santa Fe | - | Bahia - BA | 0:0 (0:0) | ||
| 1st(1st leg): 24/11/2020 22:15 | 2nd (2nd leg): 01/12/2020 22:15 | Winner: Bahia - BA | ||||
| 1st(1st leg) | Vélez Sarsfield | - | Deportivo Cali | 2:0 (0:0) | ||
| 2nd (2nd leg) | Deportivo Cali | - | Vélez Sarsfield | 1:5 (1:2) | ||
| 1st(1st leg): 25/11/2020 00:30 | 2nd (2nd leg): 02/12/2020 00:30 | Winner: Vélez Sarsfield | ||||
| 1st(1st leg) | Bolívar | - | Lanús | 2:1 (1:1) | ||
| 2nd (2nd leg) | Lanús | - | Bolívar | 6:2 (2:1) | ||
| 1st(1st leg): 25/11/2020 22:15 | 2nd (2nd leg): 02/12/2020 22:15 | Winner: Lanús | ||||
| 1st(1st leg) | Coquimbo Unido | - | Sport Huancayo | 0:0 (0:0) | ||
| 2nd (2nd leg) | Sport Huancayo | - | Coquimbo Unido | 0:2 (0:1) | ||
| 1st(1st leg): 26/11/2020 00:30 | 2nd (2nd leg): 03/12/2020 00:30 | Winner: Coquimbo Unido | ||||
| 1st(1st leg) | Fénix | - | Independiente | 1:4 (1:3) | ||
| 2nd (2nd leg) | Independiente | - | Fénix | 1:0 (1:0) | ||
| 1st(1st leg): 26/11/2020 00:30 | 2nd (2nd leg): 03/12/2020 00:30 | Winner: Independiente | ||||
| 1st(1st leg) | River Plate | - | Universidad Católica | 1:2 (1:1) | ||
| 2nd (2nd leg) | Universidad Católica | - | River Plate | 0:1 (0:0) | ||
| 1st(1st leg): 26/11/2020 22:15 | 2nd (2nd leg): 04/12/2020 00:30 | Winner: Universidad Católica | ||||
| 1st(1st leg) | Defensa y Justicia | - | Vasco da Gama - RJ | 1:1 (0:0) | ||
| 2nd (2nd leg) | Vasco da Gama - RJ | - | Defensa y Justicia | 0:1 (0:0) | ||
| 1st(1st leg): 27/11/2020 00:30 | 2nd (2nd leg): 04/12/2020 00:30 | Winner: Defensa y Justicia | ||||
| 1st(1st leg) | Atlético Junior | - | Unión La Calera | 2:1 (1:0) | ||
| 2nd (2nd leg) | Unión La Calera | - | Atlético Junior | 2:4 (1:1, 2:1) pso | ||
| 1st(1st leg): 27/11/2020 00:30 | 2nd (2nd leg): 03/12/2020 22:15 | Winner: Atlético Junior | ||||
