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| 1st(1st leg) | Independiente Medellín | - | Atlético Tucumán | 1:0 (1:0) | ||
| 2nd (2nd leg) | Atlético Tucumán | - | Independiente Medellín | 2:4 (1:0, 1:0) pso | ||
| 1st(1st leg): 19/02/2020 00:30 | 2nd (2nd leg): 26/02/2020 00:30 | Winner: Independiente Medellín | ||||
| 1st(1st leg) | Barcelona | - | Cerro Porteño | 1:0 (1:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Barcelona | 0:4 (0:1) | ||
| 1st(1st leg): 20/02/2020 00:30 | 2nd (2nd leg): 26/02/2020 22:15 | Winner: Barcelona | ||||
| 1st(1st leg) | Deportes Tolima | - | Internacional | 0:0 (0:0) | ||
| 2nd (2nd leg) | Internacional | - | Deportes Tolima | 1:0 (1:0) | ||
| 1st(1st leg): 20/02/2020 00:30 | 2nd (2nd leg): 27/02/2020 00:30 | Winner: Internacional | ||||
| 1st(1st leg) | Palestino | - | Guaraní | 0:1 (0:1) | ||
| 2nd (2nd leg) | Guaraní | - | Palestino | 2:1 (0:1) | ||
| 1st(1st leg): 20/02/2020 22:15 | 2nd (2nd leg): 27/02/2020 22:15 | Winner: Guaraní | ||||
