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| 1st(1st leg) | Newell's Old Boys | - | Vélez Sarsfield | 0:1 (0:0) | ||
| 2nd (2nd leg) | Vélez Sarsfield | - | Newell's Old Boys | 1:2 (0:2) | ||
| 1st(1st leg): 25/04/2013 01:15 | 2nd (2nd leg): 15/05/2013 23:15 | Winner: Newell's Old Boys | ||||
| 1st(1st leg) | Real Garcilaso | - | Nacional | 1:0 (1:0) | ||
| 2nd (2nd leg) | Nacional | - | Real Garcilaso | 1:4 (0:0, 1:0, 1:0) pso | ||
| 1st(1st leg): 26/04/2013 02:15 | 2nd (2nd leg): 10/05/2013 01:15 | Winner: Real Garcilaso | ||||
| 1st(1st leg) | Tigre | - | Club Olimpia | 2:1 (1:0) | ||
| 2nd (2nd leg) | Club Olimpia | - | Tigre | 2:0 (0:0) | ||
| 1st(1st leg): 01/05/2013 00:15 | 2nd (2nd leg): 17/05/2013 00:00 | Winner: Club Olimpia | ||||
| 1st(1st leg) | Club Tijuana | - | Palmeiras | 0:0 (0:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Club Tijuana | 1:2 (0:1) | ||
| 1st(1st leg): 01/05/2013 02:30 | 2nd (2nd leg): 15/05/2013 02:00 | Winner: Club Tijuana | ||||
| 1st(1st leg) | Grêmio Porto Alegre | - | Santa Fe | 2:1 (1:0) | ||
| 2nd (2nd leg) | Santa Fe | - | Grêmio Porto Alegre | 1:0 (0:0) | ||
| 1st(1st leg): 01/05/2013 23:30 | 2nd (2nd leg): 17/05/2013 02:30 | Winner: Santa Fe | ||||
| 1st(1st leg) | Boca Juniors | - | Corinthians SP | 1:0 (0:0) | ||
| 2nd (2nd leg) | Corinthians SP | - | Boca Juniors | 1:1 (0:1) | ||
| 1st(1st leg): 02/05/2013 01:50 | 2nd (2nd leg): 16/05/2013 02:00 | Winner: Boca Juniors | ||||
| 1st(1st leg) | São Paulo FC | - | Atlético Mineiro | 1:2 (1:1) | ||
| 2nd (2nd leg) | Atlético Mineiro | - | São Paulo FC | 4:1 (1:0) | ||
| 1st(1st leg): 03/05/2013 00:15 | 2nd (2nd leg): 09/05/2013 02:00 | Winner: Atlético Mineiro | ||||
| 1st(1st leg) | Emelec | - | Fluminense RJ | 2:1 (1:1) | ||
| 2nd (2nd leg) | Fluminense RJ | - | Emelec | 2:0 (1:0) | ||
| 1st(1st leg): 03/05/2013 02:30 | 2nd (2nd leg): 09/05/2013 02:00 | Winner: Fluminense RJ | ||||
