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| 1st(1st leg) | Cúcuta Deportivo | - | Nacional | 2:0 (0:0) | ||
| 2nd (2nd leg) | Nacional | - | Cúcuta Deportivo | 2:2 (1:1) | ||
| 1st(1st leg): 16/05/2007 03:00 | 2nd (2nd leg): 23/05/2007 00:15 | Winner: Cúcuta Deportivo | ||||
| 1st(1st leg) | Defensor Sporting | - | Grêmio Porto Alegre | 2:0 (2:0) | ||
| 2nd (2nd leg) | Grêmio Porto Alegre | - | Defensor Sporting | 4:2 (2:0, 2:0, 2:0) pso | ||
| 1st(1st leg): 16/05/2007 23:30 | 2nd (2nd leg): 23/05/2007 23:15 | Winner: Grêmio Porto Alegre | ||||
| 1st(1st leg) | CF América | - | Santos FC | 0:0 (0:0) | ||
| 2nd (2nd leg) | Santos FC | - | CF América | 2:1 (0:1) | ||
| 1st(1st leg): 17/05/2007 01:45 | 2nd (2nd leg): 24/05/2007 01:45 | Winner: Santos FC | ||||
| 1st(1st leg) | Boca Juniors | - | Libertad | 1:1 (0:0) | ||
| 2nd (2nd leg) | Libertad | - | Boca Juniors | 0:2 (0:0) | ||
| 1st(1st leg): 18/05/2007 01:15 | 2nd (2nd leg): 25/05/2007 01:15 | Winner: Boca Juniors | ||||
