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| 1st(1st leg) | Atlético Junior | - | Boca Juniors | 3:3 (3:1) | ||
| 2nd (2nd leg) | Boca Juniors | - | Atlético Junior | 4:0 (2:0) | ||
| 1st(1st leg): 18/05/2005 00:15 | 2nd (2nd leg): 26/05/2005 23:05 | Winner: Boca Juniors | ||||
| 1st(1st leg) | LDU Quito | - | River Plate | 2:1 (1:1) | ||
| 2nd (2nd leg) | River Plate | - | LDU Quito | 4:2 (2:0) | ||
| 1st(1st leg): 18/05/2005 02:30 | 2nd (2nd leg): 27/05/2005 01:15 | Winner: River Plate | ||||
| 1st(1st leg) | Banfield | - | Independiente Medellín | 3:0 (0:0) | ||
| 2nd (2nd leg) | Independiente Medellín | - | Banfield | 0:2 (0:0) | ||
| 1st(1st leg): 18/05/2005 23:20 | 2nd (2nd leg): 25/05/2005 01:00 | Winner: Banfield | ||||
| 1st(1st leg) | Palmeiras | - | São Paulo FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | São Paulo FC | - | Palmeiras | 2:0 (0:0) | ||
| 1st(1st leg): 19/05/2005 01:40 | 2nd (2nd leg): 26/05/2005 00:15 | Winner: São Paulo FC | ||||
| 1st(1st leg) | CF Pachuca | - | Deportivo Guadalajara | 1:1 (1:0) | ||
| 2nd (2nd leg) | Deportivo Guadalajara | - | CF Pachuca | 3:1 (1:1) | ||
| 1st(1st leg): 19/05/2005 03:50 | 2nd (2nd leg): 25/05/2005 03:30 | Winner: Deportivo Guadalajara | ||||
| 1st(1st leg) | Athletico Paranaense | - | Cerro Porteño | 2:1 (1:0) | ||
| 2nd (2nd leg) | Cerro Porteño | - | Athletico Paranaense | 4:5 (2:1, 2:1, 2:1) pso | ||
| 1st(1st leg): 19/05/2005 23:15 | 2nd (2nd leg): 26/05/2005 22:15 | Winner: Athletico Paranaense | ||||
| 1st(1st leg) | Universidad de Chile | - | Santos FC | 2:1 (0:0) | ||
| 2nd (2nd leg) | Santos FC | - | Universidad de Chile | 3:0 (1:0) | ||
| 1st(1st leg): 20/05/2005 01:30 | 2nd (2nd leg): 25/05/2005 23:45 | Winner: Santos FC | ||||
| 1st(1st leg) | Once Caldas | - | UANL Tigres | 1:1 (0:1) | ||
| 2nd (2nd leg) | UANL Tigres | - | Once Caldas | 2:1 (0:1) | ||
| 1st(1st leg): 20/05/2005 03:45 | 2nd (2nd leg): 27/05/2005 03:45 | Winner: UANL Tigres | ||||
