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| 1st(1st leg) | Unión Española | - | O'Higgins | 1:0 (1:0) | ||
| 2nd (2nd leg) | O'Higgins | - | Unión Española | 2:1 (1:0) | ||
| 1st(1st leg): 16/06/2012 21:00 | 2nd (2nd leg): 23/06/2012 21:00 | Winner: Unión Española | ||||
| 1st(1st leg) | Colo-Colo | - | Universidad de Chile | 2:0 (1:0) | ||
| 2nd (2nd leg) | Universidad de Chile | - | Colo-Colo | 4:0 (2:0) | ||
| 1st(1st leg): 17/06/2012 20:30 | 2nd (2nd leg): 24/06/2012 20:30 | Winner: Universidad de Chile | ||||
