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| 1st(1st leg) | AC Milan | - | Tottenham Hotspur | 1:0 (1:0) | ||
| 2nd (2nd leg) | Tottenham Hotspur | - | AC Milan | 0:0 (0:0) | ||
| 1st(1st leg): 14/02/2023 20:00 | 2nd (2nd leg): 08/03/2023 20:10 | Winner: AC Milan | ||||
| 1st(1st leg) | Paris Saint-Germain | - | Bayern München | 0:1 (0:0) | ||
| 2nd (2nd leg) | Bayern München | - | Paris Saint-Germain | 2:0 (0:0) | ||
| 1st(1st leg): 14/02/2023 20:00 | 2nd (2nd leg): 08/03/2023 20:00 | Winner: Bayern München | ||||
| 1st(1st leg) | Club Brugge KV | - | SL Benfica | 0:2 (0:0) | ||
| 2nd (2nd leg) | SL Benfica | - | Club Brugge KV | 5:1 (2:0) | ||
| 1st(1st leg): 15/02/2023 20:00 | 2nd (2nd leg): 07/03/2023 20:00 | Winner: SL Benfica | ||||
| 1st(1st leg) | Borussia Dortmund | - | Chelsea FC | 1:0 (0:0) | ||
| 2nd (2nd leg) | Chelsea FC | - | Borussia Dortmund | 2:0 (1:0) | ||
| 1st(1st leg): 15/02/2023 20:00 | 2nd (2nd leg): 07/03/2023 20:10 | Winner: Chelsea FC | ||||
| 1st(1st leg) | Liverpool FC | - | Real Madrid | 2:5 (2:2) | ||
| 2nd (2nd leg) | Real Madrid | - | Liverpool FC | 1:0 (0:0) | ||
| 1st(1st leg): 21/02/2023 20:00 | 2nd (2nd leg): 15/03/2023 20:00 | Winner: Real Madrid | ||||
| 1st(1st leg) | Eintracht Frankfurt | - | SSC Napoli | 0:2 (0:1) | ||
| 2nd (2nd leg) | SSC Napoli | - | Eintracht Frankfurt | 3:0 (1:0) | ||
| 1st(1st leg): 21/02/2023 20:00 | 2nd (2nd leg): 15/03/2023 20:00 | Winner: SSC Napoli | ||||
| 1st(1st leg) | RB Leipzig | - | Manchester City | 1:1 (0:1) | ||
| 2nd (2nd leg) | Manchester City | - | RB Leipzig | 7:0 (3:0) | ||
| 1st(1st leg): 22/02/2023 20:00 | 2nd (2nd leg): 14/03/2023 20:00 | Winner: Manchester City | ||||
| 1st(1st leg) | Inter | - | FC Porto | 1:0 (0:0) | ||
| 2nd (2nd leg) | FC Porto | - | Inter | 0:0 (0:0) | ||
| 1st(1st leg): 22/02/2023 20:00 | 2nd (2nd leg): 14/03/2023 20:00 | Winner: Inter | ||||
