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| 1st(1st leg) | Real Madrid | - | Arsenal FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Arsenal FC | - | Real Madrid | 0:0 (0:0) | ||
| 1st(1st leg): 21/02/2006 19:45 | 2nd (2nd leg): 08/03/2006 19:45 | Winner: Arsenal FC | ||||
| 1st(1st leg) | Bayern München | - | AC Milan | 1:1 (1:0) | ||
| 2nd (2nd leg) | AC Milan | - | Bayern München | 4:1 (2:1) | ||
| 1st(1st leg): 21/02/2006 19:45 | 2nd (2nd leg): 08/03/2006 19:45 | Winner: AC Milan | ||||
| 1st(1st leg) | PSV Eindhoven | - | Olympique Lyonnais | 0:1 (0:0) | ||
| 2nd (2nd leg) | Olympique Lyonnais | - | PSV Eindhoven | 4:0 (2:0) | ||
| 1st(1st leg): 21/02/2006 19:45 | 2nd (2nd leg): 08/03/2006 19:45 | Winner: Olympique Lyonnais | ||||
| 1st(1st leg) | SL Benfica | - | Liverpool FC | 1:0 (0:0) | ||
| 2nd (2nd leg) | Liverpool FC | - | SL Benfica | 0:2 (0:1) | ||
| 1st(1st leg): 21/02/2006 19:45 | 2nd (2nd leg): 08/03/2006 19:45 | Winner: SL Benfica | ||||
| 1st(1st leg) | Werder Bremen | - | Juventus | 3:2 (1:0) | ||
| 2nd (2nd leg) | Juventus | - | Werder Bremen | 2:1 (0:1) | ||
| 1st(1st leg): 22/02/2006 19:45 | 2nd (2nd leg): 07/03/2006 19:45 | Winner: Juventus | ||||
| 1st(1st leg) | AFC Ajax | - | Inter | 2:2 (2:0) | ||
| 2nd (2nd leg) | Inter | - | AFC Ajax | 1:0 (0:0) | ||
| 1st(1st leg): 22/02/2006 19:45 | 2nd (2nd leg): 14/03/2006 19:45 | Winner: Inter | ||||
| 1st(1st leg) | Rangers FC | - | Villarreal CF | 2:2 (1:2) | ||
| 2nd (2nd leg) | Villarreal CF | - | Rangers FC | 1:1 (0:1) | ||
| 1st(1st leg): 22/02/2006 19:45 | 2nd (2nd leg): 07/03/2006 19:45 | Winner: Villarreal CF | ||||
| 1st(1st leg) | Chelsea FC | - | FC Barcelona | 1:2 (0:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | Chelsea FC | 1:1 (0:0) | ||
| 1st(1st leg): 22/02/2006 19:45 | 2nd (2nd leg): 07/03/2006 19:45 | Winner: FC Barcelona | ||||
