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| 1st(1st leg) | Vasco da Gama | - | Internacional | 0:1 (0:0) | ||
| 2nd (2nd leg) | Internacional | - | Vasco da Gama | 3:2 (1:1) | ||
| 1st(1st leg): 14/05/2021 23:00 | 2nd (2nd leg): 23/05/2021 00:00 | Winner: Internacional | ||||
| 1st(1st leg) | Avai - SC | - | Palmeiras | 1:0 (1:0) | ||
| 2nd (2nd leg) | Palmeiras | - | Avai - SC | 1:1 (1:1) | ||
| 1st(1st leg): 16/05/2021 20:00 | 2nd (2nd leg): 22/05/2021 17:45 | Winner: Avai - SC | ||||
| 1st(1st leg) | Coritiba - PR | - | Atlético Mineiro | 2:2 (0:1) | ||
| 2nd (2nd leg) | Atlético Mineiro | - | Coritiba - PR | 0:2 (0:1) | ||
| 1st(1st leg): 17/05/2021 00:30 | 2nd (2nd leg): 22/05/2021 15:00 | Winner: Coritiba - PR | ||||
| 1st(1st leg) | Floresta - CE | - | Botafogo - RJ | 1:2 (1:2) | ||
| 2nd (2nd leg) | Botafogo - RJ | - | Floresta - CE | 3:0 (1:0) | ||
| 1st(1st leg): 18/05/2021 19:00 | 2nd (2nd leg): 23/05/2021 14:30 | Winner: Botafogo - RJ | ||||
