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| 1st(1st leg) | Fortaleza - CE | - | São Paulo FC | 3:3 (2:2) | ||
| 2nd (2nd leg) | São Paulo FC | - | Fortaleza - CE | 10:9 (1:0, 2:2) pso | ||
| 1st(1st leg): 14/10/2020 23:15 | 2nd (2nd leg): 25/10/2020 23:30 | Winner: São Paulo FC | ||||
| 1st(1st leg) | Botafogo - RJ | - | Cuiabá - MT | 0:1 (0:0) | ||
| 2nd (2nd leg) | Cuiabá - MT | - | Botafogo - RJ | 0:0 (0:0) | ||
| 1st(1st leg): 28/10/2020 00:30 | 2nd (2nd leg): 03/11/2020 22:00 | Winner: Cuiabá - MT | ||||
| 1st(1st leg) | Santos FC | - | Ceará - CE | 0:0 (0:0) | ||
| 2nd (2nd leg) | Ceará - CE | - | Santos FC | 1:0 (0:0) | ||
| 1st(1st leg): 28/10/2020 19:00 | 2nd (2nd leg): 04/11/2020 22:00 | Winner: Ceará - CE | ||||
| 1st(1st leg) | Atlético Goianiense | - | Internacional | 1:2 (0:1) | ||
| 2nd (2nd leg) | Internacional | - | Atlético Goianiense | 2:1 (0:0) | ||
| 1st(1st leg): 28/10/2020 22:00 | 2nd (2nd leg): 04/11/2020 00:30 | Winner: Internacional | ||||
| 1st(1st leg) | Athletico Paranaense | - | Flamengo RJ | 0:1 (0:1) | ||
| 2nd (2nd leg) | Flamengo RJ | - | Athletico Paranaense | 3:2 (2:1) | ||
| 1st(1st leg): 29/10/2020 00:30 | 2nd (2nd leg): 05/11/2020 00:30 | Winner: Flamengo RJ | ||||
| 1st(1st leg) | Corinthians SP | - | América - MG | 0:1 (0:0) | ||
| 2nd (2nd leg) | América - MG | - | Corinthians SP | 1:1 (0:0) | ||
| 1st(1st leg): 29/10/2020 00:30 | 2nd (2nd leg): 05/11/2020 00:30 | Winner: América - MG | ||||
| 1st(1st leg) | Red Bull Bragantino | - | Palmeiras | 1:3 (0:3) | ||
| 2nd (2nd leg) | Palmeiras | - | Red Bull Bragantino | 1:0 (1:0) | ||
| 1st(1st leg): 29/10/2020 22:00 | 2nd (2nd leg): 05/11/2020 22:00 | Winner: Palmeiras | ||||
| 1st(1st leg) | Grêmio Porto Alegre | - | Juventude - RS | 1:0 (1:0) | ||
| 2nd (2nd leg) | Juventude - RS | - | Grêmio Porto Alegre | 0:1 (0:0) | ||
| 1st(1st leg): 30/10/2020 00:30 | 2nd (2nd leg): 06/11/2020 00:30 | Winner: Grêmio Porto Alegre | ||||
