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| 1st(1st leg) | Barcelona - RO | - | Porto Velho EC - RO | 1:1 | ||
| 2nd (2nd leg) | Porto Velho EC - RO | - | Barcelona - RO | 1:0 (1:0) | ||
| 1st(1st leg): 05/04/2025 21:00 | 2nd (2nd leg): 09/04/2025 23:00 | Winner: Porto Velho EC - RO | ||||
| 1st(1st leg) | Ji-Paraná - RO | - | Guaporé - RO | 0:0 (0:0) | ||
| 2nd (2nd leg) | Guaporé - RO | - | Ji-Paraná - RO | 2:1 (1:0) | ||
| 1st(1st leg): 06/04/2025 21:00 | 2nd (2nd leg): 10/04/2025 23:30 | Winner: Guaporé - RO | ||||
