| 6. Round | 29/08/2020 | Kilmarnock FC | - | Dundee United | 4:0 | ||||
| 11. Round | 17/10/2020 | Livingston FC | - | Kilmarnock FC | 1:3 | ||||
| 12. Round | 24/10/2020 | Kilmarnock FC | - | Hibernian FC | 0:1 | ||||
| 13. Round | 01/11/2020 | Kilmarnock FC | - | Rangers FC | 0:1 | ||||
| 17. Round | 13/12/2020 | Celtic FC | - | Kilmarnock FC | 2:0 | ||||
| 19. Round | 23/12/2020 | Dundee United | - | Kilmarnock FC | 2:0 | ||||
| 20. Round | 26/12/2020 | Kilmarnock FC | - | Livingston FC | 1:2 | ||||
| 21. Round | 30/12/2020 | Motherwell FC | - | Kilmarnock FC | 0:2 | ||||
| 22. Round | 02/01/2021 | Kilmarnock FC | - | St. Mirren FC | 1:1 |  |
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| 23. Round | 09/01/2021 | Kilmarnock FC | - | Hamilton Academical | 2:0 | ||||
| 24. Round | 16/01/2021 | Hibernian FC | - | Kilmarnock FC | 2:0 | ||||
| 28. Round | 06/02/2021 | St. Mirren FC | - | Kilmarnock FC | 2:0 | ||||
| 10. Round | 10/02/2021 | Kilmarnock FC | - | Motherwell FC | 0:1 | ||||
| 29. Round | 13/02/2021 | Rangers FC | - | Kilmarnock FC | 1:0 | ||||
| 33. Round | 20/02/2021 | Aberdeen FC | - | Kilmarnock FC | 1:0 | ||||
| 32. Round | 20/03/2021 | Kilmarnock FC | - | Motherwell FC | 4:1 |
Congo DR
France 
