| Group G | 13/09/2005 | Real Betis | - | Liverpool FC | 1:2 | ||||
| Group G | 28/09/2005 | Liverpool FC | - | Chelsea FC | 0:0 |  |
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| Group G | 19/10/2005 | RSC Anderlecht | - | Liverpool FC | 0:1 | |
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| Group G | 01/11/2005 | Liverpool FC | - | RSC Anderlecht | 3:0 | ||||
| Round of 16 | 21/02/2006 | SL Benfica | - | Liverpool FC | 1:0 | ||||
| Round of 16 | 08/03/2006 | Liverpool FC | - | SL Benfica | 0:2 | |
Spain
