1. Round 30/08/1985 Valencia CF - Real Valladolid 2:1
2. Round 03/09/1985 Real Valladolid - Espanyol Barcelona 1:0
3. Round 07/09/1985 Racing Santander - Real Valladolid 1:1
4. Round 14/09/1985 Real Valladolid - Real Zaragoza 1:1
5. Round 27/09/1985 Atlético Madrid - Real Valladolid 1:4
6. Round 06/10/1985 Real Valladolid - CA Osasuna 1:0
7. Round 13/10/1985 Athletic Club - Real Valladolid 3:3
8. Round 20/10/1985 Real Valladolid - Sevilla FC 2:0
9. Round 27/10/1985 Hércules CF - Real Valladolid 1:0
10. Round 02/11/1985 Real Valladolid - FC Barcelona 2:2
11. Round 09/11/1985 Cádiz CF - Real Valladolid 1:0
12. Round 16/11/1985 Real Valladolid - UD Las Palmas 4:2
13. Round 23/11/1985 Real Valladolid - Real Madrid 3:2 Goal yellow card
14. Round 30/11/1985 RC Celta - Real Valladolid 3:2
15. Round 06/12/1985 Real Valladolid - Sporting Gijón 0:1
16. Round 14/12/1985 Real Sociedad - Real Valladolid 2:1
17. Round 21/12/1985 Real Valladolid - Real Betis 4:2
18. Round 28/12/1985 Real Valladolid - Valencia CF 3:3
19. Round 04/01/1986 Espanyol Barcelona - Real Valladolid 2:1
20. Round 11/01/1986 Real Valladolid - Racing Santander 1:0
21. Round 18/01/1986 Real Zaragoza - Real Valladolid 1:0 yellow card
22. Round 25/01/1986 Real Valladolid - Atlético Madrid 2:1
23. Round 01/02/1986 CA Osasuna - Real Valladolid 2:1
24. Round 08/02/1986 Real Valladolid - Athletic Club 0:1
25. Round 15/02/1986 Sevilla FC - Real Valladolid 1:0
26. Round 22/02/1986 Real Valladolid - Hércules CF 3:1
27. Round 28/02/1986 FC Barcelona - Real Valladolid 4:0
28. Round 08/03/1986 Real Valladolid - Cádiz CF 3:0
29. Round 14/03/1986 UD Las Palmas - Real Valladolid 1:0
30. Round 22/03/1986 Real Madrid - Real Valladolid 2:1
31. Round 29/03/1986 Real Valladolid - RC Celta 4:0 Goal
32. Round 05/04/1986 Sporting Gijón - Real Valladolid 3:0
33. Round 12/04/1986 Real Valladolid - Real Sociedad 4:1 yellow card
34. Round 19/04/1986 Real Betis - Real Valladolid 1:1