| 5. Round | 25/09/2012 | FC Schalke 04 | - | 1. FSV Mainz 05 | 3:0 |  |
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| 13. Round | 24/11/2012 | FC Schalke 04 | - | Eintracht Frankfurt | 1:1 | ||||
| 14. Round | 27/11/2012 | Hamburger SV | - | FC Schalke 04 | 3:1 | ||||
| 15. Round | 01/12/2012 | FC Schalke 04 | - | Bor. Mönchengladbach | 1:1 | ||||
| 16. Round | 08/12/2012 | VfB Stuttgart | - | FC Schalke 04 | 3:1 | ||||
| 17. Round | 15/12/2012 | FC Schalke 04 | - | SC Freiburg | 1:3 | ||||
| 20. Round | 02/02/2013 | FC Schalke 04 | - | SpVgg Greuther Fürth | 1:2 | ||||
| 21. Round | 09/02/2013 | Bayern München | - | FC Schalke 04 | 4:0 | ||||
| 22. Round | 16/02/2013 | 1. FSV Mainz 05 | - | FC Schalke 04 | 2:2 | ||||
| 25. Round | 09/03/2013 | FC Schalke 04 | - | Borussia Dortmund | 2:1 | ||||
| 26. Round | 16/03/2013 | 1. FC Nürnberg | - | FC Schalke 04 | 3:0 | ||||
| 27. Round | 30/03/2013 | FC Schalke 04 | - | 1899 Hoffenheim | 3:0 | |
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| 28. Round | 06/04/2013 | Werder Bremen | - | FC Schalke 04 | 0:2 | ||||
| 29. Round | 13/04/2013 | FC Schalke 04 | - | Bayer Leverkusen | 2:2 | |
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| 30. Round | 20/04/2013 | Eintracht Frankfurt | - | FC Schalke 04 | 1:0 | ||||
| 31. Round | 28/04/2013 | FC Schalke 04 | - | Hamburger SV | 4:1 | ||||
| 33. Round | 11/05/2013 | FC Schalke 04 | - | VfB Stuttgart | 1:2 |
Finland
