| 2. Round | 04/02/2023 | Belgrano de Córdoba | - | River Plate | 2:1 | ||||
| 3. Round | 12/02/2023 | River Plate | - | Argentinos Juniors | 2:1 | ||||
| 4. Round | 18/02/2023 | Tigre | - | River Plate | 0:1 | ||||
| 5. Round | 26/02/2023 | River Plate | - | Arsenal de Sarandí | 1:2 | ||||
| 6. Round | 04/03/2023 | Lanús | - | River Plate | 0:2 | ||||
| 7. Round | 12/03/2023 | River Plate | - | Godoy Cruz | 3:0 | ||||
| 8. Round | 20/03/2023 | Sarmiento de Junín | - | River Plate | 0:2 | ||||
| 9. Round | 01/04/2023 | River Plate | - | Unión de Santa Fe | 1:0 | ||||
| 10. Round | 09/04/2023 | Huracán | - | River Plate | 0:3 |  |
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| 11. Round | 13/04/2023 | River Plate | - | Gimnasia de La Plata | 3:0 | ||||
| 13. Round | 24/04/2023 | River Plate | - | Independiente | 2:0 | ||||
| 14. Round | 29/04/2023 | Atlético Tucumán | - | River Plate | 1:1 | ||||
| 16. Round | 15/05/2023 | Talleres de Córdoba | - | River Plate | 2:1 | ||||
| 20. Round | 12/06/2023 | Banfield | - | River Plate | 1:4 | |
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| 22. Round | 01/07/2023 | Barracas Central | - | River Plate | 2:1 | ||||
| 26. Round | 24/07/2023 | Rosario Central | - | River Plate | 3:3 | |
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| 27. Round | 29/07/2023 | River Plate | - | Racing Club | 2:1 |
Venezuela
