| 1. Round | 10/11/1999 | Córdoba CF | - | Espanyol Barcelona | 1:1 |  |
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| 1. Round | 01/12/1999 | Espanyol Barcelona | - | Córdoba CF | 2:0 | ||||
| 2. Round | 12/01/2000 | Espanyol Barcelona | - | Albacete | 2:0 | |
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| Round of 16 | 19/01/2000 | Espanyol Barcelona | - | RC Celta | 2:1 | ||||
| Round of 16 | 01/02/2000 | RC Celta | - | Espanyol Barcelona | 0:1 | ||||
| Quarter-finals | 09/02/2000 | Espanyol Barcelona | - | SD Compostela | 5:1 |  |
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| Quarter-finals | 16/02/2000 | SD Compostela | - | Espanyol Barcelona | 1:0 | |
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| Semi-finals | 12/04/2000 | Real Madrid | - | Espanyol Barcelona | 0:0 | ||||
| Semi-finals | 26/04/2000 | Espanyol Barcelona | - | Real Madrid | 1:0 | ||||
| Final | 27/05/2000 | Espanyol Barcelona | - | Atlético Madrid | 2:1 |
Spain