| Play-offs | 24/02/2022 | Maccabi Tel Aviv | - | PSV Eindhoven | 1:1 | ||||
| Round of 16 | 17/03/2022 | FC København | - | PSV Eindhoven | 0:4 | ||||
| Quarter-finals | 07/04/2022 | Leicester City | - | PSV Eindhoven | 0:0 |
| Play-offs | 24/02/2022 | Maccabi Tel Aviv | - | PSV Eindhoven | 1:1 | ||||
| Round of 16 | 17/03/2022 | FC København | - | PSV Eindhoven | 0:4 | ||||
| Quarter-finals | 07/04/2022 | Leicester City | - | PSV Eindhoven | 0:0 |
| Olivier Maxime Boscagli | |
| Born: | 18.11.1997 |
| Place of birth: |
Monaco, 
Monaco |
| Nationality: |
France
Monaco |
| Height: | 181 cm |
| Weight: | 68 kg |
| Position(s): | Centre Back Defensive Midfielder |
| Foot: | left |