| 5. Round | 24/10/2020 | Borussia Dortmund | - | FC Schalke 04 | 3:0 | ||||
| 10. Round | 05/12/2020 | Eintracht Frankfurt | - | Borussia Dortmund | 1:1 | ||||
| 11. Round | 12/12/2020 | Borussia Dortmund | - | VfB Stuttgart | 1:5 |  |
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| 12. Round | 15/12/2020 | Werder Bremen | - | Borussia Dortmund | 1:2 | ||||
| 13. Round | 18/12/2020 | 1. FC Union Berlin | - | Borussia Dortmund | 2:1 | ||||
| 18. Round | 22/01/2021 | Bor. Mönchengladbach | - | Borussia Dortmund | 4:2 | ||||
| 19. Round | 30/01/2021 | Borussia Dortmund | - | FC Augsburg | 3:1 | ||||
| 22. Round | 20/02/2021 | FC Schalke 04 | - | Borussia Dortmund | 0:4 | ||||
| 23. Round | 27/02/2021 | Borussia Dortmund | - | Arminia Bielefeld | 3:0 | ||||
| 24. Round | 06/03/2021 | Bayern München | - | Borussia Dortmund | 4:2 | ||||
| 25. Round | 13/03/2021 | Borussia Dortmund | - | Hertha BSC | 2:0 | ||||
| 28. Round | 10/04/2021 | VfB Stuttgart | - | Borussia Dortmund | 2:3 | ||||
| 29. Round | 18/04/2021 | Borussia Dortmund | - | Werder Bremen | 4:1 |
Spain