| 1. Round | 16/08/1991 | RSC Charleroi | - | KFC Germinal Ekeren | 3:1 | ||||
| 2. Round | 20/08/1991 | KSK Beveren | - | RSC Charleroi | 0:0 | ||||
| 3. Round | 27/08/1991 | RSC Charleroi | - | KSV Waregem | 1:2 | ||||
| 5. Round | 06/09/1991 | KRC Genk | - | RSC Charleroi | 3:0 | ||||
| 6. Round | 13/09/1991 | RSC Charleroi | - | KV Mechelen | 1:2 | ||||
| 7. Round | 19/09/1991 | Cercle Brugge | - | RSC Charleroi | 3:0 |  |
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| 9. Round | 05/10/1991 | KAA Gent | - | RSC Charleroi | 0:0 | |
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| 10. Round | 12/10/1991 | RSC Charleroi | - | Royal Antwerp FC | 0:1 | ||||
| 11. Round | 20/10/1991 | KV Kortrijk | - | RSC Charleroi | 2:1 |
Senegal