| 6. Round | 10/09/2022 | SSC Napoli | - | Spezia Calcio | 1:0 | ||||
| 10. Round | 16/10/2022 | SSC Napoli | - | Bologna FC | 3:2 |  |
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| 11. Round | 23/10/2022 | AS Roma | - | SSC Napoli | 0:1 | ||||
| 12. Round | 29/10/2022 | SSC Napoli | - | Sassuolo Calcio | 4:0 | ||||
| 13. Round | 05/11/2022 | Atalanta | - | SSC Napoli | 1:2 | ||||
| 15. Round | 12/11/2022 | SSC Napoli | - | Udinese Calcio | 3:2 |  |
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| 17. Round | 08/01/2023 | Sampdoria | - | SSC Napoli | 0:2 | |
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| 26. Round | 11/03/2023 | SSC Napoli | - | Atalanta | 2:0 | ||||
| 28. Round | 02/04/2023 | SSC Napoli | - | AC Milan | 0:4 | ||||
| 30. Round | 15/04/2023 | SSC Napoli | - | Hellas Verona | 0:0 | ||||
| 31. Round | 23/04/2023 | Juventus | - | SSC Napoli | 0:1 | ||||
| 32. Round | 30/04/2023 | SSC Napoli | - | US Salernitana 1919 | 1:1 | ||||
| 35. Round | 14/05/2023 | AC Monza | - | SSC Napoli | 2:0 | ||||
| 36. Round | 21/05/2023 | SSC Napoli | - | Inter | 3:1 | ||||
| 37. Round | 28/05/2023 | Bologna FC | - | SSC Napoli | 2:2 |
Brazil
Italy 
