| League phase | 17/09/2024 | Juventus | - | PSV Eindhoven | 3:1 | ||||
| League phase | 01/10/2024 | PSV Eindhoven | - | Sporting CP | 1:1 |  |
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| League phase | 21/01/2025 | Crvena Zvezda | - | PSV Eindhoven | 2:3 | ||||
| Play-offs | 11/02/2025 | Juventus | - | PSV Eindhoven | 2:1 | ||||
| Play-offs | 19/02/2025 | PSV Eindhoven | - | Juventus | 3:1 aet |  |
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| Round of 16 | 04/03/2025 | PSV Eindhoven | - | Arsenal FC | 1:7 | ||||
| Round of 16 | 12/03/2025 | Arsenal FC | - | PSV Eindhoven | 2:2 |
Netherlands