| Group B | 20/09/2023 | Arsenal FC | - | PSV Eindhoven | 4:0 | ||||
| Group B | 03/10/2023 | PSV Eindhoven | - | Sevilla FC | 2:2 | ||||
| Group B | 24/10/2023 | RC Lens | - | PSV Eindhoven | 1:1 | ||||
| Group B | 08/11/2023 | PSV Eindhoven | - | RC Lens | 1:0 | ||||
| Group B | 29/11/2023 | Sevilla FC | - | PSV Eindhoven | 2:3 |  |
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| Group B | 12/12/2023 | PSV Eindhoven | - | Arsenal FC | 1:1 | ||||
| Round of 16 | 20/02/2024 | PSV Eindhoven | - | Borussia Dortmund | 1:1 |
Spain