| 2. Round | 17/09/2020 | Borac Banja Luka | - | Rio Ave FC | 0:2 |  |
|||
| 3. Round | 24/09/2020 | Beşiktaş | - | Rio Ave FC | 2:4 pso | |
|||
| Play-offs | 01/10/2020 | Rio Ave FC | - | AC Milan | 8:9 pso | |
| 2. Round | 17/09/2020 | Borac Banja Luka | - | Rio Ave FC | 0:2 | |
|||
| 3. Round | 24/09/2020 | Beşiktaş | - | Rio Ave FC | 2:4 pso | |
|||
| Play-offs | 01/10/2020 | Rio Ave FC | - | AC Milan | 8:9 pso | |
| Filipe Augusto Carvalho Souza | |
| Born: | 12.08.1993 |
| Place of birth: |
Itambe, 
Brazil |
| Nationality: |
Brazil
|
| Height: | 183 cm |
| Weight: | 76 kg |
| Position(s): | Defensive Midfielder Central Midfielder |
| Foot: | left |