| 1. Round | 31/08/2009 | FC Barcelona | - | Sporting Gijón | 3:0 | ||||
| 2. Round | 12/09/2009 | Getafe CF | - | FC Barcelona | 0:2 | ||||
| 4. Round | 22/09/2009 | Racing Santander | - | FC Barcelona | 1:4 | ||||
| 5. Round | 26/09/2009 | Málaga CF | - | FC Barcelona | 0:2 | ||||
| 7. Round | 17/10/2009 | Valencia CF | - | FC Barcelona | 0:0 | ||||
| 9. Round | 31/10/2009 | CA Osasuna | - | FC Barcelona | 1:1 | ||||
| 10. Round | 07/11/2009 | FC Barcelona | - | RCD Mallorca | 4:2 | ||||
| 12. Round | 29/11/2009 | FC Barcelona | - | Real Madrid | 1:0 | ||||
| 13. Round | 05/12/2009 | Deportivo La Coruña | - | FC Barcelona | 1:3 |  |
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| 16. Round | 02/01/2010 | FC Barcelona | - | Villarreal CF | 1:1 | ||||
| 18. Round | 16/01/2010 | FC Barcelona | - | Sevilla FC | 4:0 | ||||
| 19. Round | 23/01/2010 | Real Valladolid | - | FC Barcelona | 0:3 | ||||
| 20. Round | 30/01/2010 | Sporting Gijón | - | FC Barcelona | 0:1 | ||||
| 21. Round | 06/02/2010 | FC Barcelona | - | Getafe CF | 2:1 | ||||
| 30. Round | 03/04/2010 | FC Barcelona | - | Athletic Club | 4:1 | ||||
| 37. Round | 08/05/2010 | Sevilla FC | - | FC Barcelona | 2:3 | ||||
| 38. Round | 16/05/2010 | FC Barcelona | - | Real Valladolid | 4:0 |
France
